Observation of a re-entrant phase transition in the molecular complex tris(μ2-3,5-diisopropyl-1,2,4-triazolato-κ2N1
Paul Raithby,
Christopher Woodall,
Jeppe Christensen,
Jonathan Skelton,
Lauren Hatcher,
Andrew Parlett,
Aron Walsh,
Stephen Parker,
Christine M. Beavers,
Simon Teat,
Mourad Intissar,
Christian Reber,
David R. Allan
Sep 01, 2016
We report a molecular crystal that exhibits four successive phase transitions under hydrostatic pressure, driven by aurophilic interactions, with the ground-state structure re-emerging at high pressure. The effect of pressure...