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Iron-Catalyzed H/D Exchange of Primary Silanes, Secondary Silanes and Tertiary Siloxanes
A synthetic study into the catalytic hydrogen/deuterium (H/D) exchange of 1° silanes, 2° silanes, and 3° siloxanes is presented, facilitated by iron-β-diketiminato complexes (1a and 1b). Near-complete H/D exchange is observed...
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Iron-Catalyzed H/D Exchange of Primary Silanes, Secondary Silanes and Tertiary Siloxanes
A synthetic study into the catalytic hydrogen/deuterium (H/D) exchange of 1° silanes, 2° silanes, and 3° siloxanes is presented, facilitated by iron-β-diketiminato complexes (1a and 1b). Near-complete H/D exchange is observed...
Published by: