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Studies on alkyne hydrophosphination employing nickel-NHC catalysts (NHC=N-heterocyclic carbene) revealed that the free N-alkyl substituted NHCs themselves were catalytically active. DFT calculations showed the mechanism...

N-heterocyclic carbene density functional calculations homogeneous catalysis hydrophosphination reaction mechanisms /dk/atira/pure/subjectarea/asjc/1500/1503 name=Catalysis /dk/atira/pure/subjectarea/asjc/1600/1606 name=Physical and Theoretical Chemistry /dk/atira/pure/subjectarea/asjc/1600/1605 name=Organic Chemistry /dk/atira/pure/subjectarea/asjc/1600/1604 name=Inorganic Chemistry

A detailed synthetic investigation into the dehydrocoupling of silanes with amines, phosphines, and alcohols using an iron precatalyst (1) is presented. We have furnished over 30 examples of aminosilane synthesis along with...

dehydrocoupling homogeneous catalysis Iron reaction mechanisms Silanes /dk/atira/pure/subjectarea/asjc/1500/1503 name=Catalysis /dk/atira/pure/subjectarea/asjc/1600/1600 name=General Chemistry

A detailed synthetic investigation into the dehydrocoupling of silanes with amines, phosphines, and alcohols using an iron precatalyst (1) is presented. We have furnished over 30 examples of aminosilane synthesis along with...

dehydrocoupling homogeneous catalysis Iron reaction mechanisms Silanes /dk/atira/pure/subjectarea/asjc/1500/1503 name=Catalysis /dk/atira/pure/subjectarea/asjc/1600/1600 name=General Chemistry

Studies on alkyne hydrophosphination employing nickel-NHC catalysts (NHC=N-heterocyclic carbene) revealed that the free N-alkyl substituted NHCs themselves were catalytically active. DFT calculations showed the mechanism...

N-heterocyclic carbene density functional calculations homogeneous catalysis hydrophosphination reaction mechanisms /dk/atira/pure/subjectarea/asjc/1500/1503 name=Catalysis /dk/atira/pure/subjectarea/asjc/1600/1606 name=Physical and Theoretical Chemistry /dk/atira/pure/subjectarea/asjc/1600/1605 name=Organic Chemistry /dk/atira/pure/subjectarea/asjc/1600/1604 name=Inorganic Chemistry

reaction mechanisms animation enzyme reaction mechanisms A BETA-LACTAMASES

A palladium(II)-catalyzed γ-C-H amination of cyclic alkyl amines to deliver highly substituted azetidines is reported. The use of a benziodoxole tosylate oxidant in combination with AgOAc was found to be crucial for controlling...

C−H activation azetidines hypervalent compounds Palladium reaction mechanisms

C−H activation Amines Decarboxylation Palladium reaction mechanisms