A seven-membered N,N′-heterocyclic potassium alumanyl nucleophile is introduced and utilised in the metathetical synthesis of Mg−Al and Ca−Al bonded derivatives. Both species have been characterised by experimental and...
The hydride complex [Ru(IPr) 2(CO)H][BAr F 4], 1, reacts with InMe 3 with loss of CH 4 to form [Ru(IPr) 2(CO)(InMe)(Me)][BAr F 4], 4...
The hydride complex [Ru(IPr) 2(CO)H][BAr F 4], 1, reacts with InMe 3 with loss of CH 4 to form [Ru(IPr) 2(CO)(InMe)(Me)][BAr F 4], 4...
The seven-membered cyclic potassium alumanyl species, [{SiN Mes}AlK] 2 [{SiN Mes}={CH 2SiMe 2N(Mes)} 2; Mes=2,4,6-Me 3C 6H 2]...
The synthesis of the Cu-borate complexes [(6Mes)Cu(HBR3)] featuring the unusual [HBEt3]− (5) and [HB(C6F5)3]− (6) ligands is described. Experimental...
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