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Inorganic and organozinc fluorocarboxylates
The organozinc fluorocarboxylates RZnO2CRf and RZnO2CRf·TMEDA, along with Zn(O2CRf)2·TMEDA (R = Me, Et; Rf = C2F5, C3F7) have been synthesized. The structures of EtZnO2C2F5 (5), EtZnO2C3F7 (7), EtZnO2C2F5·TMEDA (11)...
The first crystallographically-characterised Cu(II) xanthate

The copper(II) xanthate Cu(S2COEt)2·TMEDA (1)(TMEDA = N,N-tetramethylethylenediamine) has been synthesised and is the first structurally-characterised xanthate of...

Dreaming of flying when grounded
A.L. Fraher, Y. Gabriel
Aug 06, 2014
This article analyses the effects of job loss on the occupational identities of a group of United States pilots, laid off (or 'furloughed') twice by their employer in the decade following 9/11. Using a narrative methodology, the...
Inorganic and organozinc fluorocarboxylates
The organozinc fluorocarboxylates RZnO2CRf and RZnO2CRf·TMEDA, along with Zn(O2CRf)2·TMEDA (R = Me, Et; Rf = C2F5, C3F7) have been synthesized. The structures of EtZnO2C2F5 (5), EtZnO2C3F7 (7), EtZnO2C2F5·TMEDA (11)...
Dreaming of flying when grounded
A.L. Fraher, Y. Gabriel
Aug 06, 2014
This article analyses the effects of job loss on the occupational identities of a group of United States pilots, laid off (or 'furloughed') twice by their employer in the decade following 9/11. Using a narrative methodology, the...
Single-source AACVD of composite cobalt-silicon oxide thin films
A series of cobalt(II) complexes comprising either triorganosiloxide or tris(tert-butoxy)siloxide ligands have been synthesized and characterized. A mononuclear constitution is enforced through the incorporation of bi- and...
The first crystallographically-characterised Cu(II) xanthate

The copper(II) xanthate Cu(S2COEt)2·TMEDA (1)(TMEDA = N,N-tetramethylethylenediamine) has been synthesised and is the first structurally-characterised xanthate of...

Synthesis of heterobimetallic tungsten acetylacetonate/alkoxide complexes and their application as molecular precursors to metal tungstates

A series of MW2(O)2(acac)2 (OMe)10 [M = Co (1), Ni (2), Mg (3), Zn (4)] have been synthesised and structurally characterised by X-ray crystallography. All the compounds share common structural...

Lithium and potassium aminoalkoxides
The structures of the Group 1 metal aminoalkoxides Li[OCH(CH CNMe)] (1) and K[OCH(CHCNMe )]·H OCH(CHCNMe) (2) have been determined. 1 is a hexameric drum in which two Li O rings are joined co-facially, whereas 2 is tetrameric...
Single-source AACVD of composite cobalt-silicon oxide thin films
A series of cobalt(II) complexes comprising either triorganosiloxide or tris(tert-butoxy)siloxide ligands have been synthesized and characterized. A mononuclear constitution is enforced through the incorporation of bi- and...
Synthesis and structures of Cu-Cl-M adducts (M = Zn, Sn, Sb)

The novel bimetallic adducts [(Ph3P)2CuCl]2.ZnCl2 (1), {[(Me3P)CuCl]2.ZnCI2l}n (2)...

Synthesis and structures of Cu-Cl-M adducts (M = Zn, Sn, Sb)

The novel bimetallic adducts [(Ph3P)2CuCl]2.ZnCl2 (1), {[(Me3P)CuCl]2.ZnCI2l}n (2)...

Lithium and potassium aminoalkoxides
The structures of the Group 1 metal aminoalkoxides Li[OCH(CH CNMe)] (1) and K[OCH(CHCNMe )]·H OCH(CHCNMe) (2) have been determined. 1 is a hexameric drum in which two Li O rings are joined co-facially, whereas 2 is tetrameric...
Synthesis of heterobimetallic tungsten acetylacetonate/alkoxide complexes and their application as molecular precursors to metal tungstates

A series of MW2(O)2(acac)2 (OMe)10 [M = Co (1), Ni (2), Mg (3), Zn (4)] have been synthesised and structurally characterised by X-ray crystallography. All the compounds share common structural...

Photoactivated linkage isomerism in single crystals of nickel, palladium and platinum di-nitro complexes
Low temperature, single crystal photocrystallographic studies have been carried out on four square planar Group 10 complexes Ni(PEt 3) 2(NO 2) 2] 1, [Pd(PPh 3) 2(NO 2) 2] 2, [Pd(AsPh 3) 2(NO 2) 2] 3 and [Pt(PPh 3) 2(NO 2) 2] 4...
Photoactivated linkage isomerism in single crystals of nickel, palladium and platinum di-nitro complexes
Low temperature, single crystal photocrystallographic studies have been carried out on four square planar Group 10 complexes Ni(PEt 3) 2(NO 2) 2] 1, [Pd(PPh 3) 2(NO 2) 2] 2, [Pd(AsPh 3) 2(NO 2) 2] 3 and [Pt(PPh 3) 2(NO 2) 2] 4...
New di-ferrocenyl-ethynylpyridinyl triphenylphosphine copper halide complexes and related di-ferricenyl electro-crystallized materials
Three new neutral di-ferrocenyl-ethynylpyridinyl copper complexes, [L (CuCl)(PPh)] (2), [L (CuBr)(PPh)] (3), and [L (CuI)(PPh)] (4) were synthesized from the ferrocenyl-ethynylpyridine ligand (L) (1), the appropriate copper...
Screening for potential co-products in a <em>Miscanthus</em> <em>sinensis</em> mapping family by liquid chromatography with mass spectrometry detection

Society is demanding more green chemicals from sustainable sources. Miscanthus is a potential source of platform chemicals and bioethanol through fermentation. Miscanthus sinensis (M. sinensis) has...

New di-ferrocenyl-ethynylpyridinyl triphenylphosphine copper halide complexes and related di-ferricenyl electro-crystallized materials
Three new neutral di-ferrocenyl-ethynylpyridinyl copper complexes, [L (CuCl)(PPh)] (2), [L (CuBr)(PPh)] (3), and [L (CuI)(PPh)] (4) were synthesized from the ferrocenyl-ethynylpyridine ligand (L) (1), the appropriate copper...
Screening for potential co-products in a <em>Miscanthus</em> <em>sinensis</em> mapping family by liquid chromatography with mass spectrometry detection

Society is demanding more green chemicals from sustainable sources. Miscanthus is a potential source of platform chemicals and bioethanol through fermentation. Miscanthus sinensis (M. sinensis) has...

Solid-state interconversions
The solid-state, low-temperature linkage isomerism in a series of five square planar group 10 phosphino nitro complexes have been investigated by a combination of photocrystallographic experiments, Raman spectroscopy and...
Solid-state interconversions
The solid-state, low-temperature linkage isomerism in a series of five square planar group 10 phosphino nitro complexes have been investigated by a combination of photocrystallographic experiments, Raman spectroscopy and...

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