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A heteroleptic diradical Cr(iii) complex with extended spin delocalization and large intramolecular magnetic exchange
Xiaozhou Ma, Elizaveta A. Suturina, Mathieu Rouzières, Fabrice Wilhelm, Andrei Rogalev, Rodolphe Clérac, Pierre Dechambenoit
May 04, 2020
Successive chemical reductions of the heteroleptic complex [(tpy)Cr III(tphz)] 3+(tpy = terpyridine; tphz = tetrapyridophenazine) give rise to the mono- and di-radical redox isomers, [(tpy)Cr...
Using Redox-Active πbridging Ligand as a Control Switch of Intramolecular Magnetic Interactions
Xiaozhou Ma, Elizaveta A. Suturina, Mathieu Rouzières, Mikhail Platunov, Fabrice Wilhelm, Andrei Rogalev, Rodolphe Clérac, Pierre Dechambenoit
May 15, 2019
Intramolecular magnetic interactions in the dinuclear complexes [(tpy)Ni(tphz)Ni(tpy)]n+ (n = 4, 3, and 2; tpy, terpyridine; tphz, tetrapyridophenazine) were tailored by changing the oxidation state of the...
A heteroleptic diradical Cr(iii) complex with extended spin delocalization and large intramolecular magnetic exchange
Xiaozhou Ma, Elizaveta A. Suturina, Mathieu Rouzières, Fabrice Wilhelm, Andrei Rogalev, Rodolphe Clérac, Pierre Dechambenoit
May 04, 2020
Successive chemical reductions of the heteroleptic complex [(tpy)Cr III(tphz)] 3+(tpy = terpyridine; tphz = tetrapyridophenazine) give rise to the mono- and di-radical redox isomers, [(tpy)Cr...
Using Redox-Active πbridging Ligand as a Control Switch of Intramolecular Magnetic Interactions
Xiaozhou Ma, Elizaveta A. Suturina, Mathieu Rouzières, Mikhail Platunov, Fabrice Wilhelm, Andrei Rogalev, Rodolphe Clérac, Pierre Dechambenoit
May 15, 2019
Intramolecular magnetic interactions in the dinuclear complexes [(tpy)Ni(tphz)Ni(tpy)]n+ (n = 4, 3, and 2; tpy, terpyridine; tphz, tetrapyridophenazine) were tailored by changing the oxidation state of the...
Metal-organic magnets with large coercivity and ordering temperatures up to 242°C
Panagiota Perlepe, Itziar Oyarzabal, Aaron Mailman, Morgane Yquel, Mikhail Platunov, Iurii Dovgaliuk, Mathieu Rouzières, Philippe Négrier, Denise Mondieig, Elizaveta A. Suturina, Marie-Anne Dourges, Sébastien Bonhommeau, Rebecca A. Musgrave, Kasper S. Pedersen, Dmitry Chernyshov, Fabrice Wilhelm, Andrei Rogalev, Corine Mathonière, Rodolphe Clérac
Oct 30, 2020
Magnets derived from inorganic materials (e.g., oxides, rare-earth–based, and intermetallic compounds) are key components of modern technological applications. Despite considerable success in a broad range of applications, these...
Metal-organic magnets with large coercivity and ordering temperatures up to 242°C
Panagiota Perlepe, Itziar Oyarzabal, Aaron Mailman, Morgane Yquel, Mikhail Platunov, Iurii Dovgaliuk, Mathieu Rouzières, Philippe Négrier, Denise Mondieig, Elizaveta A. Suturina, Marie-Anne Dourges, Sébastien Bonhommeau, Rebecca A. Musgrave, Kasper S. Pedersen, Dmitry Chernyshov, Fabrice Wilhelm, Andrei Rogalev, Corine Mathonière, Rodolphe Clérac
Oct 30, 2020
Magnets derived from inorganic materials (e.g., oxides, rare-earth–based, and intermetallic compounds) are key components of modern technological applications. Despite considerable success in a broad range of applications, these...
Dynamics of Information Networks
We explore a simple model of network dynamics which has previously been applied to the study of information flow in the context of epidemic spreading. A random rooted network is constructed that evolves according to the...
Triangulations of monotone families I
Let K⊂Rn be a compact definable set in an o-minimal structure over R, for example, a semi-algebraic or a subanalytic set. A definable family {Sδ|0<δ∈R} of compact subsets of K is called a monotone family if Sδ⊂Sη for all...
CoSMed
This paper describes progress with our agenda of formal verification of information flow security for realistic systems. We present CoSMed, a social media platform with verified document confidentiality. The system’s kernel is...
Stochastic drift in discrete waves of nonlocally interacting particles
In this paper, we investigate a generalized model of N particles undergoing second-order nonlocal interactions on a lattice. Our results have applications across many research areas, including the modeling of migration...
Triangulations of monotone families I
Let K⊂Rn be a compact definable set in an o-minimal structure over R, for example, a semi-algebraic or a subanalytic set. A definable family {Sδ|0<δ∈R} of compact subsets of K is called a monotone family if Sδ⊂Sη for all...
SMEs and Certified Management Standards
Existing research on certifiable management standards (CMS) and corporate social responsibility (CSR) tends to focus on large companies and is characterised by disagreement about the role of these standards as drivers of CSR. We...
Dynamics of Information Networks
We explore a simple model of network dynamics which has previously been applied to the study of information flow in the context of epidemic spreading. A random rooted network is constructed that evolves according to the...
NNLO QCD study of polarised W + W − production at the LHC
Abstract: Longitudinal polarisation of the weak bosons is a direct consequence of Electroweak symmetry breaking mechanism providing an insight into its nature, and is instrumental in searches for physics beyond the Standard...
Health impact modelling of active travel visions for England and Wales using an Integrated Transport and Health Impact Modelling Tool (ITHIM).
BACKGROUND: Achieving health benefits while reducing greenhouse gas emissions from transport offers a potential policy win-win; the magnitude of potential benefits, however, is likely to vary. This study uses an Integrated...
SMEs and Certified Management Standards
Existing research on certifiable management standards (CMS) and corporate social responsibility (CSR) tends to focus on large companies and is characterised by disagreement about the role of these standards as drivers of CSR. We...
Noise-activated barrier crossing in multi-attractor spiking networks
Noise-activated transitions between coexisting attractors are investigated in a chaotic spiking network. At low noise level, attractor hopping consists of discrete bifurcation events that conserve the memory of initial...
Noise-activated barrier crossing in multi-attractor spiking networks
Noise-activated transitions between coexisting attractors are investigated in a chaotic spiking network. At low noise level, attractor hopping consists of discrete bifurcation events that conserve the memory of initial...
Stochastic drift in discrete waves of nonlocally interacting particles
In this paper, we investigate a generalized model of N particles undergoing second-order nonlocal interactions on a lattice. Our results have applications across many research areas, including the modeling of migration...
Phase editing as a signal pre-processing step for automated bearing fault detection
Leonardo Barbini, Agusmian P. Ompusunggu, Andrei Bartic, Andrew Hillis, Jonathan Du Bois
Jul 01, 2017
Scheduled maintenance and inspection of bearing elements in industrial machinery contributes significantly to the operating costs. Savings can be made through automatic vibration-based damage detection and prognostics, to permit...
Task difficulty of virtual reality-based assessment tools compared to classical paper-and-pencil or computerized measures
Virtual reality-based assessment tools arise as a promising alternative for classic neuropsychological assessment with an increased level of ecological validity. Because virtual reality cognitive measures recreate tasks that...
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