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Magnesium-catalysed hydroboration of isonitriles
A beta-diketiminato magnesium alkyl complex is shown to be an effective pre-catalyst for the first reported catalytic hydroboration of organic isonitriles, RNC, with HBpin. The reaction proceeds under mild conditions when R =...
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Facile kinetic induction of a dihydropyridide to pyrrolide ring contraction
Reactions between magnesium 1,4-dihydropyridide or 1,2-dihydro-iso-quinolide derivatives and carbodiimides, RN=C=NR, generally result in Mg-N insertion and formation of guanidinate complexes. More sterically perturbed systems...
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Facile kinetic induction of a dihydropyridide to pyrrolide ring contraction
Reactions between magnesium 1,4-dihydropyridide or 1,2-dihydro-iso-quinolide derivatives and carbodiimides, RN=C=NR, generally result in Mg-N insertion and formation of guanidinate complexes. More sterically perturbed systems...
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Magnesium-catalysed hydroboration of isonitriles
A beta-diketiminato magnesium alkyl complex is shown to be an effective pre-catalyst for the first reported catalytic hydroboration of organic isonitriles, RNC, with HBpin. The reaction proceeds under mild conditions when R =...
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Magnesium-catalysed hydroboration of pyridines
A kinetic analysis of the hydroboration of iso-quinoline with pinacol borane (HBpin) and catalysed by a β-diketiminato magnesium n-butyl pre-catalyst has provided evidence that the reaction proceeds via rate determining Mg–N/H–B...
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Magnesium-catalysed hydroboration of pyridines
A kinetic analysis of the hydroboration of iso-quinoline with pinacol borane (HBpin) and catalysed by a β-diketiminato magnesium n-butyl pre-catalyst has provided evidence that the reaction proceeds via rate determining Mg–N/H–B...
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Magnesium hydrides and the dearomatisation of pyridine and quinoline derivatives
Reactions of the -diketiminato n-butyl magnesium complex, [HC{(Me)CN(2,6-iPr2C6H3)} 2MgnBu], with a range of substituted pyridines and fused-ring quinolines in the presence of PhSiH3 has been found to result in dearomatisation...
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Magnesium hydrides and the dearomatisation of pyridine and quinoline derivatives
Reactions of the -diketiminato n-butyl magnesium complex, [HC{(Me)CN(2,6-iPr2C6H3)} 2MgnBu], with a range of substituted pyridines and fused-ring quinolines in the presence of PhSiH3 has been found to result in dearomatisation...
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Potentials of Reflection for Better Practice
This chapter describes how adult learners in competency-based degree programs learn to reflect actively on their learning and performance. Vignettes of adult learners portray what they perceive as the benefits of reflective...
Drives and Motives During Online Degree Completion
Catherine Cherrstrom
Jan 01, 2024
This study examined the motives and drives of adult students during online degree completion, including the commonalities among and differences between Hispanic and non-Hispanic adult students. Participants included 364 adult...
Citizenship and Social Studies Curricula in British Columbia, Canada
Catherine Broom
Jan 31, 2020
This chapter begins by reviewing the history of citizenship education in social studies curricula in British Columbia (BC), Canada, as a way of framing how the topic has been understood. It then discusses the latest curriculum...
Twenty-First Century Immersion Technologies in Health Professions Pedagogy
Catherine Hayes
Jul 01, 2024
This encyclopedia entry provides insight into the justification of pedagogy in the context of extended reality (XR), which itself encompasses virtual reality (VR), augmented reality (AR), and mixed/hybrid reality (MR), and how...
Digital Social Media in Adolescents' Negotiating Real Virtual Romantic Relationships
Previous grounded theoretical analyses of rural adolescents' romantic relationship discussions identified media as critical conditions in negotiating gender expectations in intimate relations. More recent emergent fit analyses...
Ed Tech in Adult Online Learning
Educational technology facilitates convenient access to online programs for adult students but also presents challenges. Using a conceptual framework of Knowles' andragogy process of program development and learner interaction...
Selective reduction of CO<sub>2</sub> to a methanol equivalent by B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>-activated alkaline earth catalysis
Treatment of β-diketiminato Mg and Ca amidoborane compounds with B(CF) induces hydride elimination and formation of alkaline earth hydrido-tris(pentafluorophenyl)borate derivatives. Both species react with CO to provide formate...
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Self-Directed/Community-Supported Learning
MOOC designers seeking to address evolving ambitions of MOOCs to support workforce development confront a fundamental design dilemma: on the one hand, the self-paced nature of online learning is efficient for busy learners...
The ‘ownership’ of science
C Rhodes, J Harris, S Chan, J Sulston
Aug 10, 2017
Dr Catherine Rhodes is a research fellow at the Institute for Science, Ethics and Innovation specialising in the international regulations relevant to control of biotechnology. Professor John Harris is director of the Institute...
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Selective reduction of CO<sub>2</sub> to a methanol equivalent by B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>-activated alkaline earth catalysis
Treatment of β-diketiminato Mg and Ca amidoborane compounds with B(CF) induces hydride elimination and formation of alkaline earth hydrido-tris(pentafluorophenyl)borate derivatives. Both species react with CO to provide formate...
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Learning, Adults, and Competency-Based Education
Because competency-based education (CBE) programs ask students to demonstrate what they know and can do and because CBE students often work at their own pace, competence-based learners need to be able to articulate and to manage...
Concept of Temporal Pretopology for the Analysis for Structural Changes
Pretopology is a mathematical model developed from a weakening of the topological axiomatic. It was initially used in economic, social and biological sciences and next in pattern recognition and image analysis. More recently, it...

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