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Reductive Elimination at Carbon under Steric Control

It has been previously demonstrated that stable singlet electrophilic carbenes can behave as metal surrogates in the activation of strong E-H bonds (E = H, B, N, Si, P), but it was believed that these activations only proceed...

Reductive Elimination at Carbon under Steric Control

It has been previously demonstrated that stable singlet electrophilic carbenes can behave as metal surrogates in the activation of strong E-H bonds (E = H, B, N, Si, P), but it was believed that these activations only proceed...

N-Heterocyclic Carbene Non-Innocence in the Catalytic Hydrophosphination of Alkynes

Studies on alkyne hydrophosphination employing nickel-NHC catalysts (NHC=N-heterocyclic carbene) revealed that the free N-alkyl substituted NHCs themselves were catalytically active. DFT calculations showed the mechanism...

Experimental and Computational Studies of Ruthenium Complexes Bearing Z-Acceptor Aluminum-Based Phosphine Pincer Ligands

Reaction of [Ru(C 6H 4PPh 2) 2(Ph 2PC 6H 4AlMe(THF))H] with CO results in clean conversion to the Ru-Al heterobimetallic complex [Ru(AlMePhos)(CO)...

N-Heterocyclic Carbene Non-Innocence in the Catalytic Hydrophosphination of Alkynes

Studies on alkyne hydrophosphination employing nickel-NHC catalysts (NHC=N-heterocyclic carbene) revealed that the free N-alkyl substituted NHCs themselves were catalytically active. DFT calculations showed the mechanism...

Experimental and Computational Studies of Ruthenium Complexes Bearing Z-Acceptor Aluminum-Based Phosphine Pincer Ligands

Reaction of [Ru(C 6H 4PPh 2) 2(Ph 2PC 6H 4AlMe(THF))H] with CO results in clean conversion to the Ru-Al heterobimetallic complex [Ru(AlMePhos)(CO)...

[Ni(NHC)2] as a scaffold for structurally characterized trans [H-Ni-PR2] and trans [R2P-Ni-PR2] complexes
The addition of PPh2H, PPhMeH, PPhH2, P(para-Tol)H2, PMesH2 and PH3 to the two-coordinate Ni0 N-heterocyclic carbene species [Ni(NHC)2] (NHC=IiPr2, IMe4, IEt2Me2) affords a series of mononuclear, terminal phosphido nickel...
[Ni(NHC)2] as a scaffold for structurally characterized trans [H-Ni-PR2] and trans [R2P-Ni-PR2] complexes
The addition of PPh2H, PPhMeH, PPhH2, P(para-Tol)H2, PMesH2 and PH3 to the two-coordinate Ni0 N-heterocyclic carbene species [Ni(NHC)2] (NHC=IiPr2, IMe4, IEt2Me2) affords a series of mononuclear, terminal phosphido nickel...
Non-invasive technical investigation of english portrait miniatures attributed to Nicholas Hilliard and Isaac Oliver
This study presents the results of the technical investigation carried out on several English portrait miniatures painted in the 16th and 17th century by Nicholas Hilliard and Isaac Oliver, two of the most famous limners...
Model U.N. Conference to Focus on Peace, Security and Development
Winthrop University
Jan 01, 0001
Isaac Wohl will speak at 7 p.m. March 20 in Tillman Auditorium. This is the 37th annual Model U.N. conference.
Published by: Winthrop University
Proximate Breast Cancer Factors Using Data Mining Classification Techniques
Breast cancer is the most common of all cancers and is the leading cause of cancer deaths in women worldwide. The classification of breast cancer data can be useful to predict the outcome of some diseases or discover the genetic...
Efficacy of Electronic Monitoring
Isaac Elking
Oct 18, 2022
The use of electronic performance monitoring is becoming increasingly widespread in conjunction with the digitalization of today's supply chains, yet the efficacy of these systems to improve desired performance outcomes is still...
Proximate Breast Cancer Factors Using Data Mining Classification Techniques
Breast cancer is the most common of all cancers and is the leading cause of cancer deaths in women worldwide. The classification of breast cancer data can be useful to predict the outcome of some diseases or discover the genetic...
Progressive Era Activism for Black Orphanage
Isaac L. Godoy
Apr 01, 2020
A group of American citizens that are historically overlooked and underserved are impoverished and homeless children. According to the United States Census Bureau as of 2017, when this group is divided by race, the number of...

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