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Periodicity of Single-Molecule Magnet Behaviour of Heterotetranuclear Lanthanide Complexes across the Lanthanide Series
Acetato-bridged palladium-lanthanide tetranuclear heterometallic complexes of the form [Pd2 Ln2 (H2 O)2 (CH3 COO)10 ]⋅2 CH3 COOH [Ln2 =Ce2 (1), Pr2 (2), Nd2 (3), Sm2 (4), Tb2 (5), Dy2 (6), Dy0.2 Y1.8 (6''), Ho2 (7), Er2 (8)...
An Organic–Inorganic Hybrid Exhibiting Electrical Conduction and Single‐Ion Magnetism
The first three–dimensional (3D) conductive single-ion magnet (SIM), (TTF)2[Co(pdms)2] (TTF = tetrathiafulvalene and H2pdms = 1,2-bis(methanesulfonamido)benzene), was electrochemically synthesized and investigated structurally...