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Cover Image for catena-Poly triphenyltin(IV) -mu-phenylphosphinato-kappa(2)O View Article
catena-Poly triphenyltin(IV) -mu-phenylphosphinato-kappa(2)O
T Diop, L Diop, Gabriele Kociok-Kohn, Kieran C Molloy, H Stoeckli-Evans
Dec 01, 2011
In the structure of the title coordination polymer, [Sn(C(6)H(5))(3)-(C(6)H(6)O(2)P)](n) or [PhP(H)O(2)Sn(IV)(Ph)(3)](n), the Sn(IV) atom is five-coordinate, with the SnC(3)O(2) framework in a trans trigonal-bipyramidal...
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Cover Image for catena-Poly triphenyltin(IV) -mu-phenylphosphinato-kappa(2)O View Article
catena-Poly triphenyltin(IV) -mu-phenylphosphinato-kappa(2)O
T Diop, L Diop, Gabriele Kociok-Kohn, Kieran C Molloy, H Stoeckli-Evans
Dec 01, 2011
In the structure of the title coordination polymer, [Sn(C(6)H(5))(3)-(C(6)H(6)O(2)P)](n) or [PhP(H)O(2)Sn(IV)(Ph)(3)](n), the Sn(IV) atom is five-coordinate, with the SnC(3)O(2) framework in a trans trigonal-bipyramidal...
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Cover Image for Investigation of the H<sub>2</sub>O sensing mechanism of DC operated chemiresistors based on graphene oxide and thermally reduced graphene oxide View Article
Investigation of the H<sub>2</sub>O sensing mechanism of DC operated chemiresistors based on graphene oxide and thermally reduced graphene oxide
Sotirios Papamatthaiou, Dimitrios-P. Argyropoulos, Filippos Farmakis, Nikolaos Georgoulas
Sep 15, 2019

Graphene oxide (GO) is a promising material for H 2O vapour sensing. However, the H 2O sensing mechanisms are still under investigation especially in the case of thermally reduced GO. To this purpose...

reduced graphene oxide activation energy electronic conduction ionic conduction relative humidity sensor thermal reduction /dk/atira/pure/subjectarea/asjc/3100/3105 name=Instrumentation /dk/atira/pure/subjectarea/asjc/2200/2208 name=Electrical and Electronic Engineering
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Cover Image for Investigation of the H<sub>2</sub>O sensing mechanism of DC operated chemiresistors based on graphene oxide and thermally reduced graphene oxide View Article
Investigation of the H<sub>2</sub>O sensing mechanism of DC operated chemiresistors based on graphene oxide and thermally reduced graphene oxide
Sotirios Papamatthaiou, Dimitrios-P. Argyropoulos, Filippos Farmakis, Nikolaos Georgoulas
Sep 15, 2019

Graphene oxide (GO) is a promising material for H 2O vapour sensing. However, the H 2O sensing mechanisms are still under investigation especially in the case of thermally reduced GO. To this purpose...

reduced graphene oxide activation energy electronic conduction ionic conduction relative humidity sensor thermal reduction /dk/atira/pure/subjectarea/asjc/3100/3105 name=Instrumentation /dk/atira/pure/subjectarea/asjc/2200/2208 name=Electrical and Electronic Engineering
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Cover Image for Aqueous Au-Pd colloids catalyze selective CH<sub>4</sub> oxidation to CH<sub>3</sub>OH with O<sub>2</sub> under mild conditions View Article
Aqueous Au-Pd colloids catalyze selective CH<sub>4</sub> oxidation to CH<sub>3</sub>OH with O<sub>2</sub> under mild conditions
Nishtha Agarwal, Simon J Freakley, Rebecca U McVicker, Sultan M Althahban, Nikolaos Dimitratos, Qian He, David J Morgan, Robert L Jenkins, David J Willock, Stuart H Taylor, Christopher J Kiely, Graham J. Hutchings
Oct 13, 2017
The selective oxidation of methane, the primary component of natural gas, remains an important challenge in catalysis. We used colloidal gold-palladium nanoparticles, rather than the same nanoparticles supported on titanium...
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Cover Image for Aqueous Au-Pd colloids catalyze selective CH<sub>4</sub> oxidation to CH<sub>3</sub>OH with O<sub>2</sub> under mild conditions View Article
Aqueous Au-Pd colloids catalyze selective CH<sub>4</sub> oxidation to CH<sub>3</sub>OH with O<sub>2</sub> under mild conditions
Nishtha Agarwal, Simon J Freakley, Rebecca U McVicker, Sultan M Althahban, Nikolaos Dimitratos, Qian He, David J Morgan, Robert L Jenkins, David J Willock, Stuart H Taylor, Christopher J Kiely, Graham J. Hutchings
Oct 13, 2017
The selective oxidation of methane, the primary component of natural gas, remains an important challenge in catalysis. We used colloidal gold-palladium nanoparticles, rather than the same nanoparticles supported on titanium...
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Cover Image for Selective oxidation of salicylic alcohol to aldehyde with O<sub>2</sub>/H<sub>2</sub> using Au-Pd on titanate nanotubes catalysts View Article
Selective oxidation of salicylic alcohol to aldehyde with O<sub>2</sub>/H<sub>2</sub> using Au-Pd on titanate nanotubes catalysts
Laura Torrente-Murciano, Thomas Villager, David Chadwick
Mar 01, 2015

Alcohol oxidation with 100% selectivity to the aldehyde product (versus acid formation) is achieved at mild conditions by a tandem-type system where the intermediate species of hydrogen peroxide formation from an...

gold Hydrogen Peroxide Palladium Selective oxidation Tandem reactions
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Cover Image for Engineering short, strong, charge-assisted hydrogen bonds in benzoic acid dimers through co-crystallisation with proton sponge View Article
Engineering short, strong, charge-assisted hydrogen bonds in benzoic acid dimers through co-crystallisation with proton sponge
Lynne H. Thomas, Andrew O. F. Jones, Andras A. Kallay, Garry J. Mcintyre, Chick C. Wilson
Apr 06, 2016
A series of molecular complexes of the proton sponge 1,8-bis(dimethylamino)naphthalene (DMAN) with mono-substituted halobenzoic acids are reported, illustrating the designed exploitation of the characteristics of the proton...
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Cover Image for The direct synthesis of hydrogen peroxide from H<sub>2</sub> and O<sub>2</sub> using Pd-Ni/TiO<sub>2</sub> catalysts View Article
The direct synthesis of hydrogen peroxide from H<sub>2</sub> and O<sub>2</sub> using Pd-Ni/TiO<sub>2</sub> catalysts
David A. Crole, Ricci Underhill, Jennifer K. Edwards, Greg Shaw, Simon J. Freakley, Graham J. Hutchings, Richard J. Lewis
Jul 24, 2020

The direct synthesis of hydrogen peroxide (H2O2) from molecular H2 and O2 offers an attractive, decentralized alternative to production compared to the current means of production, the anthraquinone process. Herein we...

Green chemistry Hydrogen Peroxide Nanoparticles Nickel Palladium /dk/atira/pure/subjectarea/asjc/2600/2600 name=General Mathematics /dk/atira/pure/subjectarea/asjc/2200/2200 name=General Engineering /dk/atira/pure/subjectarea/asjc/3100/3100 name=General Physics and Astronomy /dk/atira/pure/sustainabledevelopmentgoals/decent_work_and_economic_growth name=SDG 8 - Decent Work and Economic Growth /dk/atira/pure/sustainabledevelopmentgoals/responsible_consumption_and_production name=SDG 12 - Responsible Consumption and Production
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Cover Image for Noncovalent Interactions in the Oxazaborolidine-Catalyzed Enantioselective Mukaiyama Aldol View Article
Noncovalent Interactions in the Oxazaborolidine-Catalyzed Enantioselective Mukaiyama Aldol
Elliot H. E. Farrar, Matthew N. Grayson
Aug 05, 2022
Current models for oxazaborolidine-catalyzed transition-state structures are determined by C–H···O–B and C–H···O═S formyl hydrogen bonding between the electrophile and catalyst. However, selectivity in the...
/dk/atira/pure/subjectarea/asjc/1600/1605 name=Organic Chemistry
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Cover Image for Selective oxidation of salicylic alcohol to aldehyde with O<sub>2</sub>/H<sub>2</sub> using Au-Pd on titanate nanotubes catalysts View Article
Selective oxidation of salicylic alcohol to aldehyde with O<sub>2</sub>/H<sub>2</sub> using Au-Pd on titanate nanotubes catalysts
Laura Torrente-Murciano, Thomas Villager, David Chadwick
Mar 01, 2015

Alcohol oxidation with 100% selectivity to the aldehyde product (versus acid formation) is achieved at mild conditions by a tandem-type system where the intermediate species of hydrogen peroxide formation from an...

gold Hydrogen Peroxide Palladium Selective oxidation Tandem reactions
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Cover Image for Noncovalent Interactions in the Oxazaborolidine-Catalyzed Enantioselective Mukaiyama Aldol View Article
Noncovalent Interactions in the Oxazaborolidine-Catalyzed Enantioselective Mukaiyama Aldol
Elliot H. E. Farrar, Matthew N. Grayson
Aug 05, 2022
Current models for oxazaborolidine-catalyzed transition-state structures are determined by C–H···O–B and C–H···O═S formyl hydrogen bonding between the electrophile and catalyst. However, selectivity in the...
/dk/atira/pure/subjectarea/asjc/1600/1605 name=Organic Chemistry
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Cover Image for The direct synthesis of hydrogen peroxide from H<sub>2</sub> and O<sub>2</sub> using Pd-Ni/TiO<sub>2</sub> catalysts View Article
The direct synthesis of hydrogen peroxide from H<sub>2</sub> and O<sub>2</sub> using Pd-Ni/TiO<sub>2</sub> catalysts
David A. Crole, Ricci Underhill, Jennifer K. Edwards, Greg Shaw, Simon J. Freakley, Graham J. Hutchings, Richard J. Lewis
Jul 24, 2020

The direct synthesis of hydrogen peroxide (H2O2) from molecular H2 and O2 offers an attractive, decentralized alternative to production compared to the current means of production, the anthraquinone process. Herein we...

Green chemistry Hydrogen Peroxide Nanoparticles Nickel Palladium /dk/atira/pure/subjectarea/asjc/2600/2600 name=General Mathematics /dk/atira/pure/subjectarea/asjc/2200/2200 name=General Engineering /dk/atira/pure/subjectarea/asjc/3100/3100 name=General Physics and Astronomy /dk/atira/pure/sustainabledevelopmentgoals/decent_work_and_economic_growth name=SDG 8 - Decent Work and Economic Growth /dk/atira/pure/sustainabledevelopmentgoals/responsible_consumption_and_production name=SDG 12 - Responsible Consumption and Production
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Cover Image for Removal of antiretroviral drugs stavudine and zidovudine in water under UV<sub>254</sub> and UV<sub>254</sub>/H<sub>2</sub>O<sub>2</sub> processes View Article
Removal of antiretroviral drugs stavudine and zidovudine in water under UV<sub>254</sub> and UV<sub>254</sub>/H<sub>2</sub>O<sub>2</sub> processes
Danilo Russo, Antonietta Siciliano, Marco Guida, Roberto Andreozzi, Nuno M. Reis, Gianluca Li Puma, Raffaele Marotta
May 05, 2018

The concentration of antiretroviral drugs in wastewater treatment plants (WWTP) effluents and surface waters of many countries has increased significantly due to their widespread use for HIV treatment. In this study, the...

antiretroviral Genotoxicity Microreactor Mutagenicity photodegradation Stavudine Water reuse Zidovudine /dk/atira/pure/subjectarea/asjc/2300/2305 name=Environmental Engineering /dk/atira/pure/subjectarea/asjc/2300/2304 name=Environmental Chemistry /dk/atira/pure/subjectarea/asjc/2300/2311 name=Waste Management and Disposal /dk/atira/pure/subjectarea/asjc/2300/2310 name=Pollution /dk/atira/pure/subjectarea/asjc/2300/2307 name=Health, Toxicology and Mutagenesis /dk/atira/pure/sustainabledevelopmentgoals/good_health_and_well_being name=SDG 3 - Good Health and Well-being
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Cover Image for Engineering short, strong, charge-assisted hydrogen bonds in benzoic acid dimers through co-crystallisation with proton sponge View Article
Engineering short, strong, charge-assisted hydrogen bonds in benzoic acid dimers through co-crystallisation with proton sponge
Lynne H. Thomas, Andrew O. F. Jones, Andras A. Kallay, Garry J. Mcintyre, Chick C. Wilson
Apr 06, 2016
A series of molecular complexes of the proton sponge 1,8-bis(dimethylamino)naphthalene (DMAN) with mono-substituted halobenzoic acids are reported, illustrating the designed exploitation of the characteristics of the proton...
Published by:
Cover Image for Removal of antiretroviral drugs stavudine and zidovudine in water under UV<sub>254</sub> and UV<sub>254</sub>/H<sub>2</sub>O<sub>2</sub> processes View Article
Removal of antiretroviral drugs stavudine and zidovudine in water under UV<sub>254</sub> and UV<sub>254</sub>/H<sub>2</sub>O<sub>2</sub> processes
Danilo Russo, Antonietta Siciliano, Marco Guida, Roberto Andreozzi, Nuno M. Reis, Gianluca Li Puma, Raffaele Marotta
May 05, 2018

The concentration of antiretroviral drugs in wastewater treatment plants (WWTP) effluents and surface waters of many countries has increased significantly due to their widespread use for HIV treatment. In this study, the...

antiretroviral Genotoxicity Microreactor Mutagenicity photodegradation Stavudine Water reuse Zidovudine /dk/atira/pure/subjectarea/asjc/2300/2305 name=Environmental Engineering /dk/atira/pure/subjectarea/asjc/2300/2304 name=Environmental Chemistry /dk/atira/pure/subjectarea/asjc/2300/2311 name=Waste Management and Disposal /dk/atira/pure/subjectarea/asjc/2300/2310 name=Pollution /dk/atira/pure/subjectarea/asjc/2300/2307 name=Health, Toxicology and Mutagenesis /dk/atira/pure/sustainabledevelopmentgoals/good_health_and_well_being name=SDG 3 - Good Health and Well-being
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Cover Image for The Direct Synthesis of H <sub>2</sub> O <sub>2</sub> Using TS-1 Supported Catalysts View Article
The Direct Synthesis of H <sub>2</sub> O <sub>2</sub> Using TS-1 Supported Catalysts
Richard J. Lewis, Kenji Ueura, Yukimasa Fukuta, Simon J. Freakley, Liqun Kang, Ryan Wang, Qian He, Jennifer K. Edwards, David J. Morgan, Yasushi Yamamoto, Graham J. Hutchings
Mar 20, 2019

In this study we show that using AuPd nanoparticles supported on a commercial titanium silicate (TS-1) prepared using a wet co-impregnation method it is possible to produce hydrogen peroxide from molecular H 2 and...

Au−Pd-Pt Green chemistry Hydrogen Peroxide TS-1 /dk/atira/pure/subjectarea/asjc/1500/1503 name=Catalysis /dk/atira/pure/subjectarea/asjc/1600/1606 name=Physical and Theoretical Chemistry /dk/atira/pure/subjectarea/asjc/1600/1605 name=Organic Chemistry /dk/atira/pure/subjectarea/asjc/1600/1604 name=Inorganic Chemistry
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Cover Image for Precise control of Cu$_2$O nanostructures and LED-assisted photocatalysis View Article
Precise control of Cu$_2$O nanostructures and LED-assisted photocatalysis
Y Su, A Nathan, H Ma, H Wang
Oct 18, 2016
We describe the synthesis and characterization of a high-efficiency visible light Cu$_2$O photocatalyst. Uniform cubic, octahedral and rhombic dodecahedral Cu$_2$O nanocrystals with a size of 300–600 nm were synthesized using a...
7 Affordable and Clean Energy
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Cover Image for Reactivity of bis(cyclohexylammonium) 4-nitrophenylphosphate with SnMe<sub>3</sub>Cl. X-ray structure of 4-NO<sub>2 </sub>C<sub>6</sub> H<sub>4</sub> PO<sub>4</sub>(SnMe<sub>3</sub>)<sub>2·</sub>H<sub>2</sub>O View Article
Reactivity of bis(cyclohexylammonium) 4-nitrophenylphosphate with SnMe<sub>3</sub>Cl. X-ray structure of 4-NO<sub>2 </sub>C<sub>6</sub> H<sub>4</sub> PO<sub>4</sub>(SnMe<sub>3</sub>)<sub>2·</sub>H<sub>2</sub>O
W. Diallo, L. Diop, K.C. Molloy, M.F. Mahon, L. Plasseraud
Apr 01, 2014

The reaction of bis(cyclohexylammonium) 4-nitrophenylphosphate with Me3 SnCl (1:2) under reflux in ethanol yielded the title compound 4-NO2
C6 H4...

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Cover Image for Size-Dependent Visible Light Photocatalytic Performance of Cu<sub>2</sub>O Nanocubes View Article
Size-Dependent Visible Light Photocatalytic Performance of Cu<sub>2</sub>O Nanocubes
Sekar Karthikeyan, Santosh Kumar, Lee J. Durndell, Mark A. Isaacs, Christopher M.A. Parlett, Ben Coulson, Richard E. Douthwaite, Zhi Jiang, Karen Wilson, Adam F. Lee
Aug 21, 2018

Well-defined Cu2O nanocubes with tunable dimensions and physicochemical properties have been prepared using a simple one-pot reaction. Reduction of Cu(II) salts by ascorbic acid in the presence of PEG as a...

CuO Hydrogen Nanocubes Phenol photocatalysis /dk/atira/pure/subjectarea/asjc/1500/1503 name=Catalysis /dk/atira/pure/subjectarea/asjc/1600/1606 name=Physical and Theoretical Chemistry /dk/atira/pure/subjectarea/asjc/1600/1605 name=Organic Chemistry /dk/atira/pure/subjectarea/asjc/1600/1604 name=Inorganic Chemistry
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Cover Image for Hydroxide Salts in the Clouds of Venus View Article
Hydroxide Salts in the Clouds of Venus
PB Rimmer, S Jordan, T Constantinou, P Woitke, O Shorttle, R Hobbs, A Paschodimas
Jul 28, 2021
Abstract The depletion of SO2 and H2O in and above the clouds of Venus (45–65 km) cannot be explained by known gas-phase chemistry and the...
500 planetary science
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Cover Image for The synthesis and characterisation of coordination and hydrogen-bonded networks based on 4-(3,5-dimethyl-1H-pyrazol-4-yl)benzoic acid View Article
The synthesis and characterisation of coordination and hydrogen-bonded networks based on 4-(3,5-dimethyl-1H-pyrazol-4-yl)benzoic acid
MacGuire R. Bryant, Andrew D. Burrows, Christopher M. Fitchett, Chris S. Hawes, Sally O. Hunter, Luke L. Keenan, David J. Kelly, Paul E. Kruger, Mary F. Mahon, Christopher Richardson
May 21, 2015

The synthesis, structural and thermal characterisation of a number of coordination complexes featuring the N,O-heteroditopic ligand 4-(3,5-dimethyl-1H-pyrazol-4-yl)benzoate, HL are reported. The reaction of H2L...

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Cover Image for Reactivity of bis(cyclohexylammonium) 4-nitrophenylphosphate with SnMe<sub>3</sub>Cl. X-ray structure of 4-NO<sub>2 </sub>C<sub>6</sub> H<sub>4</sub> PO<sub>4</sub>(SnMe<sub>3</sub>)<sub>2·</sub>H<sub>2</sub>O View Article
Reactivity of bis(cyclohexylammonium) 4-nitrophenylphosphate with SnMe<sub>3</sub>Cl. X-ray structure of 4-NO<sub>2 </sub>C<sub>6</sub> H<sub>4</sub> PO<sub>4</sub>(SnMe<sub>3</sub>)<sub>2·</sub>H<sub>2</sub>O
W. Diallo, L. Diop, K.C. Molloy, M.F. Mahon, L. Plasseraud
Apr 01, 2014

The reaction of bis(cyclohexylammonium) 4-nitrophenylphosphate with Me3 SnCl (1:2) under reflux in ethanol yielded the title compound 4-NO2
C6 H4...

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Cover Image for Size-Dependent Visible Light Photocatalytic Performance of Cu<sub>2</sub>O Nanocubes View Article
Size-Dependent Visible Light Photocatalytic Performance of Cu<sub>2</sub>O Nanocubes
Sekar Karthikeyan, Santosh Kumar, Lee J. Durndell, Mark A. Isaacs, Christopher M.A. Parlett, Ben Coulson, Richard E. Douthwaite, Zhi Jiang, Karen Wilson, Adam F. Lee
Aug 21, 2018

Well-defined Cu2O nanocubes with tunable dimensions and physicochemical properties have been prepared using a simple one-pot reaction. Reduction of Cu(II) salts by ascorbic acid in the presence of PEG as a...

CuO Hydrogen Nanocubes Phenol photocatalysis /dk/atira/pure/subjectarea/asjc/1500/1503 name=Catalysis /dk/atira/pure/subjectarea/asjc/1600/1606 name=Physical and Theoretical Chemistry /dk/atira/pure/subjectarea/asjc/1600/1605 name=Organic Chemistry /dk/atira/pure/subjectarea/asjc/1600/1604 name=Inorganic Chemistry
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Cover Image for Synthesis, characterisation and crystal structure of [(CH<sub>3</sub>)<sub>2</sub>CH]<sub>2</sub>NH<sub>2</sub>(PhPO<sub>3</sub>H)<sub>2</sub>SnPh<sub>3</sub> View Article
Synthesis, characterisation and crystal structure of [(CH<sub>3</sub>)<sub>2</sub>CH]<sub>2</sub>NH<sub>2</sub>(PhPO<sub>3</sub>H)<sub>2</sub>SnPh<sub>3</sub>
T. Diop, L. Diop, K.C. Molloy, Gabriele Kociok-Kohn, D. Fall
Sep 01, 2012
The title compound, [(CH)CH]NH ·[(PhPOH)SnPh]-, has been synthesised and its structure determined by spectroscopies (IR, RMN and Mössbauer) and single crystal X-ray crystallography. The Mössbauer spectroscopy data for the title...
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