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Barriers to ecological restoration in Europe
J Cortina-Segarra, I García-Sánchez, M Grace, P Andrés, S Baker, C Bullock, K Decleer, LV Dicks, JL Fisher, J Frouz, A Klimkowska, AP Kyriazopoulos, D Moreno-Mateos, PM Rodríguez-González, S Sarkki, JL Ventocilla
Jun 05, 2021
Ecological restoration is key to counteracting anthropogenic degradation of biodiversity and to reducing disaster risk. However, there is limited knowledge of barriers hindering the wider implementation of restoration practices...
Integrating phenotype ontologies with PhenomeNET.
BACKGROUND: Integration and analysis of phenotype data from humans and model organisms is a key challenge in building our understanding of normal biology and pathophysiology. However, the range of phenotypes and anatomical...
Brain Tumor Imaging
Modern imaging techniques, particularly functional imaging techniques that interrogate some specific aspect of underlying tumor biology, have enormous potential in neuro-oncology for disease detection, grading, and tumor...
Controlled In-Cell Generation of Active Palladium(0) Species for Bioorthogonal Decaging.
Juraj Konč, Valerio Sabatino, Ester Jiménez-Moreno, Eloah Latocheski, Laura Rodríguez Pérez, Jason Day, Josiel B Domingos, Gonçalo JL Bernardes
Nov 09, 2021
Owing to their bioorthogonality, transition metals have become very popular in the development of biocompatible bond-cleavage reactions. However, many approaches require design and synthesis of complex ligands or formulation of...
Coordination chemistry of the bench-stable tris-2-pyridyl pnictogen ligands [E(6-Me-2-py)3] (E = As, As[double bond, length as m-dash]O, Sb).
Alex J Plajer, Daniel Crusius, Rajesh B Jethwa, Álvaro García-Romero, Andrew D Bond, Raúl García-Rodríguez, Dominic S Wright
Aug 19, 2021
Tripodal ligands with main group bridghead units are well established in coordination chemistry and single-site organometallic catalysis. Although a large number of tris(2-pyridyl) main group ligands [E(2-py)3] (E = main group...
Synthesis, structure and paramagnetic NMR analysis of a series of lanthanide-containing [LnTi6O3(OiPr)9(salicylate)6] cages
The influence of paramagnetic Ln3+ ions on the NMR behaviour is investigated via a series of new isostructural lanthanide-containing cages with the general formula [LnTi6O3(OiPr)9(salicylate)6] (Ln-1, Ln = La, Ce, Pr, Nd, Sm...
Isomerisation, reactivity and coordination chemistry of a new hybrid, multi-functional phosphazane.
Alex J Plajer, Kevin Bold, Felix J Rizzuto, Raúl García-Rodríguez, Tanya K Ronson, Dominic S Wright
Jan 17, 2018
The unsymmetric PIII/PV cyclodiphosphazane framework [(S[double bond, length as m-dash])(H)P(μ-NtBu)2PNHtBu] (2) provides entry into the mixed chalgogenide dianion [(S)P(μ-NtBu)2P(Se)NtBu]2-, and unique insight into the...
Facile synthesis of a nickel(0) phosphine complex at ambient temperature.
Schirin Hanf, Toni Grell, Jessica E Waters, Raúl García-Rodríguez, Evamarie Hey-Hawkins, Dominic S Wright
Jun 17, 2020
The reaction of the bis(methoxy)-2-pyridyl-phosphine (MeO)2P(2-py) (1) with [Ni(MeCN)6](BF4)2 leads to the unexpected single-step reduction of NiII and the formation of a tetrahedral nickel(0) complex...
A versatile hard-soft N/S-ligand for metal coordination and cluster formation.
Callum GM Benson, Alex J Plajer, Raúl García-Rodríguez, Andrew D Bond, Sanjay Singh, Lutz H Gade, Dominic S Wright
Jan 09, 2018
Deprotonation of the thialdiphosphazane [S[double bond, length as m-dash]PH(μ-N(t)Bu)]2 with a range of metal-bases gives the stable dianion [S-P(μ-N(t)Bu)]2(2-), which is valence-isoelectronic with the widely-used...
Phosphoinositide 3-kinase beta controls replication factor C assembly and function.
Javier Redondo-Muñoz, María Josefa Rodríguez, Virginia Silió, Vicente Pérez-García, José María Valpuesta, Ana C Carrera
Apr 16, 2019
Genomic integrity is preserved by the action of protein complexes that control DNA homeostasis. These include the sliding clamps, trimeric protein rings that are arranged around DNA by clamp loaders. Replication factor C (RFC)...
Machine learning-selected variables associated with CD4 T cell recovery under antiretroviral therapy in very advanced HIV infection
Abstract
Background
A considerable portion of the HIV pandemic is composed of people under antiretroviral therapy, many of whom get a late diagnosis. Patients...
Dámaris P Romero-Rodríguez, Carlos Ramírez, Iván Imaz-Rosshandler, Christopher E Ormsby, Amy Peralta-Prado, Gustavo Olvera-García, Fernanda Cervantes, Daniela Würsch-Molina, Jessica Romero-Rodríguez, Wei Jiang, Gustavo Reyes-Terán, Enrique Espinosa
Apr 23, 2021
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