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Results: 93
A Systematic Review of Animal Models of NAFLD Finds High‐Fat, High‐Fructose Diets Most Closely Resemble Human NAFLD
Background and Aims: Animal models of human disease are a key component of translational hepatology research, yet there is no consensus on which model is optimal for NAFLD. Approach and Results: We generated a database of 3,920...
Published by: Hepatology
Structural injustice
Maeve McKeown
Jun 18, 2021
Abstract: The concept of “structural injustice” has a long intellectual lineage, but Iris Marion Young popularised the term in her late work in the 2000s. Young’s theory tapped into the zeitgeist of the time, providing a...
Published by: Philosophy Compass
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A series of monopyrrolidine metal complexes have been prepared with the aim of elucidating structure-to-activity relationships for the ROP of lactide. Complexes of Li(I), Mg(II), Zn(II) and Zr(IV) were synthesised and fully...

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Ring opening copolymerization using simple Fe(III) complexes and metal- and halide-free organic catalysts
A comprehensive range of fourteen synthetically simple, air-stable and structurally diverse Fe(III) complexes, comprising of salalen, salen, salan and thiolen frameworks, were applied as catalysts to the ring opening...
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Ring opening copolymerization using simple Fe(III) complexes and metal- and halide-free organic catalysts
A comprehensive range of fourteen synthetically simple, air-stable and structurally diverse Fe(III) complexes, comprising of salalen, salen, salan and thiolen frameworks, were applied as catalysts to the ring opening...
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Polymers of Intrinsic Microporosity in the Design of Electrochemical Multi-Component and Multi-Phase Interfaces
Polymers of Intrinsic Microporosity (or PIMs) provide porous materials due to their highly contorted and rigid macromolecu-lar structures, which prevent space-efficient packing. PIMs are readily dissolved in solvents and can be...
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Making the cut

A series of monopyrrolidine metal complexes have been prepared with the aim of elucidating structure-to-activity relationships for the ROP of lactide. Complexes of Li(I), Mg(II), Zn(II) and Zr(IV) were synthesised and fully...

Published by:
Polymers of Intrinsic Microporosity (PIMs) in Triphasic Electrochemistry:
Polymers of intrinsic microporosity (PIMs) as molecularly rigid polymers have emerged as a new class of gas permeable glassy materials. They offer excellent processability and a range of potential applications also in...
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Aluminium Salalens vs. Salans
We report the rationallised design of aluminium initiators and their application for ROP of rac-lactide (rac-LA). Very minor change to the ligand backbone (imine reduction) to give secondary amines was found to have a dramatic...
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Aluminium Salalens vs. Salans
We report the rationallised design of aluminium initiators and their application for ROP of rac-lactide (rac-LA). Very minor change to the ligand backbone (imine reduction) to give secondary amines was found to have a dramatic...
Published by:
Polymers of Intrinsic Microporosity in the Design of Electrochemical Multi-Component and Multi-Phase Interfaces
Polymers of Intrinsic Microporosity (or PIMs) provide porous materials due to their highly contorted and rigid macromolecu-lar structures, which prevent space-efficient packing. PIMs are readily dissolved in solvents and can be...
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ECL sensor for selective determination of citrate ions as a prostate cancer biomarker using polymer of intrinsic microporosity-1 nanoparticles/nitrogen-doped carbon quantum dots

Urine citrate analysis is relevant in the screening and monitoring of patients with prostate cancer and calcium nephrolithiasis. A sensitive, fast, easy, and low-maintenance electrochemiluminescence (ECL) method with...

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Fuel cell anode catalyst performance can be stabilized with a molecularly rigid film of polymers of intrinsic microporosity (PIM)

There remains a major materials challenge in maintaining the performance of platinum (Pt) anode catalysts in fuel cells due to corrosion and blocking of active sites. Herein, we report a new materials strategy for improving...

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High density heterogenisation of molecular electrocatalysts in a rigid intrinsically microporous polymer host

A water-insoluble Polymer with Intrinsic Microporosity (or PIM, here for the particular case of the Tröger Base system PIM-EA-TB, BET area ca. 103 m2 -1g) is demonstrated to act as a rigid...

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Intrinsically porous polymer protects catalytic gold particles for enzymeless glucose oxidation

The enzymeless glucose oxidation process readily occurs on nano-gold electrocatalyst at pH7, but it is highly susceptible to poisoning (competitive binding), for example from protein or chloride. Is it shown here that gold...

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Polymers of Intrinsic Microporosity (PIMs) in Triphasic Electrochemistry:
Polymers of intrinsic microporosity (PIMs) as molecularly rigid polymers have emerged as a new class of gas permeable glassy materials. They offer excellent processability and a range of potential applications also in...
Published by:
ECL sensor for selective determination of citrate ions as a prostate cancer biomarker using polymer of intrinsic microporosity-1 nanoparticles/nitrogen-doped carbon quantum dots

Urine citrate analysis is relevant in the screening and monitoring of patients with prostate cancer and calcium nephrolithiasis. A sensitive, fast, easy, and low-maintenance electrochemiluminescence (ECL) method with...

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Aminopiperidine based complexes for lactide polymerisation
Herein we report the synthesis and characterisation of a series of salalen and salan ligands derived from 2-(aminomethyl)piperidine. Depending on the choice of starting salicylaldehyde, a bicyclic salan type ligand (1-3H2) or...
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Synthesis of Zn(II) and Al(III) complexes of diaminocyclohexane derived ligands and their exploitation for the ring opening polymerization of rac-lactide
Two series of ligands based on diaminocyclohexane (DACH) have been prepared and successfully complexed to Al(III) and Zn(II) metal centres. Solution and solid-state studies reveal a tendency to form mono- or bis-ligated forms...
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