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Coordination chemistry of the bench-stable tris-2-pyridyl pnictogen ligands [E(6-Me-2-py)3] (E = As, As[double bond, length as m-dash]O, Sb).
Tripodal ligands with main group bridghead units are well established in coordination chemistry and single-site organometallic catalysis. Although a large number of tris(2-pyridyl) main group ligands [E(2-py)3] (E = main group...
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Genetically raised serum bilirubin levels and lung cancer
Background: Moderately raised serum bilirubin levels are associated with lower rates of lung cancer, particularly among smokers. It is not known whether these relationships reflect antioxidant properties or residual confounding....
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Facile synthesis of a nickel(0) phosphine complex at ambient temperature.
The reaction of the bis(methoxy)-2-pyridyl-phosphine (MeO)2P(2-py) (1) with [Ni(MeCN)6](BF4)2 leads to the unexpected single-step reduction of NiII and the formation of a tetrahedral nickel(0) complex...
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Towards controlling the solid state valence tautomeric interconversion character by solvation
ABSTRACT: Crystals of [Co(diox)2(4-NO2-py)2] (1) and [Co(diox)2(4-CN-py)2] (2) where diox are the o-dioxolene 3,5-di-tbutylsemiquinonate(SQ•-) and/or 3,5-di-t-butylcatecholate (Cat2-) ions, 4-NO2-py is 4-nitro-pyridine, 4-CN-py...
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Towards controlling the solid state valence tautomeric interconversion character by solvation
ABSTRACT: Crystals of [Co(diox)2(4-NO2-py)2] (1) and [Co(diox)2(4-CN-py)2] (2) where diox are the o-dioxolene 3,5-di-tbutylsemiquinonate(SQ•-) and/or 3,5-di-t-butylcatecholate (Cat2-) ions, 4-NO2-py is 4-nitro-pyridine, 4-CN-py...
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New C∧N∧C Bis-Cyclometalated Platinum(II) Complexes
The reaction of a new ligand, ethyl 2,6-diphenylisonicotinate (EtO(2)C-CAN boolean AND C-H(2)), with K(2)PtCl(4) in acetic acid affords the monocyclometalated complex [{(EtO(2)C-CANAC-H)Pt(mu-Cl)}(2)] (1), which transforms to...
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New C∧N∧C Bis-Cyclometalated Platinum(II) Complexes
The reaction of a new ligand, ethyl 2,6-diphenylisonicotinate (EtO(2)C-CAN boolean AND C-H(2)), with K(2)PtCl(4) in acetic acid affords the monocyclometalated complex [{(EtO(2)C-CANAC-H)Pt(mu-Cl)}(2)] (1), which transforms to...
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Genetically raised serum bilirubin levels and lung cancer
BACKGROUND: Moderately raised serum bilirubin levels are associated with lower rates of lung cancer, particularly among smokers. It is not known whether these relationships reflect antioxidant properties or residual confounding....
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XAS and EPR in Situ Observation of Ru(V) Oxo Intermediate in a Ru Water Oxidation Complex.
In this study, we combine in situ spectroelectrochemistry coupled with electron paramagnetic resonance (EPR) and X-ray absorption spectroscopies (XAS) to investigate a molecular Ru-based water oxidation catalyst bearing a...
Published by: ChemElectroChem
Preparation of stereoregular isotactic poly(mandelic acid) through organocatalytic ring-opening polymerization of a cyclic O-carboxyanhydride
Poly(mandelic acid) (PMA) is an aryl analogue of poly(lactic acid) (PLA) and a biodegradable analogue of polystyrene. The preparation of stereoregular PMA was realized using a pyridine/mandelic acid adduct (Py⋅MA) as an...
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Impact of Irradiation on the Pharmacokinetics and Biotransformation of Tamoxifen.
BACKGROUND: The optimal procedure for combining radiotherapy (RT) with tamoxifen treatment is controversial as RT may alter the pharmacokinetics and biotransformation of tamoxifen. The present study investigated this potential...
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Understanding Customer Motivation to Share Information in Social Commerce
The gradual emergence of social commerce is enhancing the development of businesses. The opinions exchanged and information shared by each consumer in the community affects consumers’ purchasing decisions and participation...
The Online Betting Behavior of Sport Lottery Consumers
The sports lottery industry is growing globally, especially in the online betting market. This study focuses on online sports lottery behavior and tries to propose a framework applied in a virtual environment. Based on the...
The Effects of Navigation Cues and Involvement of Highly Innovative Consumers on Attitudes Toward Mobile Application Stores
In the e-commerce area, navigation cues play an important role that guides consumers while they are browsing products in online stores. Best-seller lists and product categories are typically used as navigation cues. With the...
Nitric Oxide Synthase Neurons in the Preoptic Hypothalamus Are NREM and REM Sleep-Active and Lower Body Temperature.
When mice are exposed to external warmth, nitric oxide synthase (NOS1) neurons in the median and medial preoptic (MnPO/MPO) hypothalamus induce sleep and concomitant body cooling. However, how these neurons regulate baseline...
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