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Conjugated poly-ynes and poly(metalla-ynes) incorporating thiophene-based spacers for solar cell (SC) applications

Solar cells (SCs) are of considerable current research interest because of their potential as a clean alternative to fossil fuels. Researchers across the globe are developing novel polymeric materials with enhanced power...

The Rise of Conjugated Poly-ynes and Poly(Metalla-ynes)
Conjugated poly-ynes and poly(metalla-ynes) constitute an important class of new materials with potential application in various domains of science. The key factors responsible for the diverse usage of these materials is their...
The Rise of Conjugated Poly-ynes and Poly(Metalla-ynes)
Conjugated poly-ynes and poly(metalla-ynes) constitute an important class of new materials with potential application in various domains of science. The key factors responsible for the diverse usage of these materials is their...
Novel Heating-Induced Reversion during Crystallization of Al-based Glassy Alloys.
Thermal stability and crystallization of three multicomponent glassy alloys, Al86Y7Ni5Co1Fe0.5Pd0.5, Al85Y8Ni5Co1Fe0.5Pd0.5 and Al84Y9Ni4Co1.5Fe0.5Pd1, were examined to assess the ability to form the mixture of amorphous (am)...
Two is Better Than One? Investigating the Effect of Incorporating Re(CO)<sub>3</sub>Cl Side-Chains into Pt(II) Diynes and Polyynes
Pt(II) di-ynes and poly-ynes incorporating 5,5’- and 6,6’-disubstituted 2,2’-bipyridines were prepared following conventional Sonogashira and Hagihara dehydrohalogenation reaction protocols. Using Pt(II) dimers and polymers as a...
Conjugated poly-ynes and poly(metalla-ynes) incorporating thiophene-based spacers for solar cell (SC) applications

Solar cells (SCs) are of considerable current research interest because of their potential as a clean alternative to fossil fuels. Researchers across the globe are developing novel polymeric materials with enhanced power...

Synthesis and structural characterization of hexa-μ<sub>2</sub>-chlorido-μ<sub>4</sub>-oxido-tetrakis{[4-(phenylethynyl)pyridine-κN]copper(II)} dichloromethane monosolvate

In the crystal structure of the title compound, [Cu4Cl6O(C13H9N)4]·CH2Cl2, the core molecular structure consists of a Cu4 tetrahedron with a central interstitial O atom. Each edge of the Cu4 tetrahedron is bridged by a...

Synthesis and structural characterization of hexa-μ<sub>2</sub>-chlorido-μ<sub>4</sub>-oxido-tetrakis{[4-(phenylethynyl)pyridine-κN]copper(II)} dichloromethane monosolvate

In the crystal structure of the title compound, [Cu4Cl6O(C13H9N)4]·CH2Cl2, the core molecular structure consists of a Cu4 tetrahedron with a central interstitial O atom. Each edge of the Cu4 tetrahedron is bridged by a...

Two is Better Than One? Investigating the Effect of Incorporating Re(CO)<sub>3</sub>Cl Side-Chains into Pt(II) Diynes and Polyynes
Pt(II) di-ynes and poly-ynes incorporating 5,5’- and 6,6’-disubstituted 2,2’-bipyridines were prepared following conventional Sonogashira and Hagihara dehydrohalogenation reaction protocols. Using Pt(II) dimers and polymers as a...
The impact of the alkyne substitution pattern and metalation on the photo-isomerization of azobenzene-based platinum(II) diynes and polyynes
Trimethylsilyl-protected di-alkynes incorporating azobenzene linker groups, Me3Si─C≡C─R─C≡C─SiMe3 (R = azobenzene-3,3’-diyl, azobenzene-4,4’-diyl, 2,5-bisoctylazobenzene-4,4’-diyl), and the corresponding terminal dialkynes...
The impact of the alkyne substitution pattern and metalation on the photo-isomerization of azobenzene-based platinum(II) diynes and polyynes
Trimethylsilyl-protected di-alkynes incorporating azobenzene linker groups, Me3Si─C≡C─R─C≡C─SiMe3 (R = azobenzene-3,3’-diyl, azobenzene-4,4’-diyl, 2,5-bisoctylazobenzene-4,4’-diyl), and the corresponding terminal dialkynes...
Dicopper(I) Complexes Incorporating Acetylide-functionalized Pyridinyl-based Ligands:
Hetero-aryl incorporated acetylide-functionalized pyridinyl ligands (L1-6) with the general formula Py-C≡C-Ar (Py = pyridine and Ar = thiophene-2-yl, 2,2'-bithiophene]-5-yl, 2,2':5',2''-terthiophene]-5-yl...
Dicopper(I) Complexes Incorporating Acetylide-functionalized Pyridinyl-based Ligands:
Hetero-aryl incorporated acetylide-functionalized pyridinyl ligands (L1-6) with the general formula Py-C≡C-Ar (Py = pyridine and Ar = thiophene-2-yl, 2,2'-bithiophene]-5-yl, 2,2':5',2''-terthiophene]-5-yl...
Synthesis, characterization, and optoelectronic properties of phenothiazine-based organic co-poly-ynes

We present the synthesis and characterization of seven new organic co-poly-ynes P1-P7 incorporating the phenothiazine (PTZ) motif and evaluate their optoelectronic properties and performance in polymer light-emitting diodes...

Synthesis, characterization, and optoelectronic properties of phenothiazine-based organic co-poly-ynes

We present the synthesis and characterization of seven new organic co-poly-ynes P1-P7 incorporating the phenothiazine (PTZ) motif and evaluate their optoelectronic properties and performance in polymer light-emitting diodes...

Ambiphilic Al‐Cu Bonding
Copper‐alumanyl complexes, [LCu‐Al(SiN Dipp )], where L = carbene = NHC iPr (N,Nʹ‐di‐isopropyl‐4,5‐dimethyl‐2‐ylidene) and Me2 CAAC (1‐(2,6‐di‐isopropylphenyl)‐3,3,5,5‐tetramethyl‐pyrrolidin‐2‐ylidene) and featuring unsupported...
Ambiphilic Al‐Cu Bonding
Copper‐alumanyl complexes, [LCu‐Al(SiN Dipp )], where L = carbene = NHC iPr (N,Nʹ‐di‐isopropyl‐4,5‐dimethyl‐2‐ylidene) and Me2 CAAC (1‐(2,6‐di‐isopropylphenyl)‐3,3,5,5‐tetramethyl‐pyrrolidin‐2‐ylidene) and featuring unsupported...

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