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Oxidative Addition to Sn(II) Guanidinate Complexes

SnS, SnSe and SnTe are potentially important semiconductor materials. Here, we describe the application of chalcogen containing Sn IV guanidinate precursors for the production of tin(II) chalcogenide nanocrystals....

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Abundance of Cu<sub>Zn</sub> + Sn<sub>Zn</sub> and 2Cu<sub>Zn</sub> + Sn<sub>Zn</sub> defect clusters in kesterite solar cells
Kesterite solar cells show the highest efficiency when the absorber layers (Cu ZnSnS [CZTS], Cu ZnSnSe [CZTSe] and their alloys) are non-stoichiometric with Cu / (Zn + Sn) ≈ 0.8 and Zn / Sn ≈ 1.2. The fundamental cause is so far...
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Abundance of Cu<sub>Zn</sub> + Sn<sub>Zn</sub> and 2Cu<sub>Zn</sub> + Sn<sub>Zn</sub> defect clusters in kesterite solar cells
Kesterite solar cells show the highest efficiency when the absorber layers (Cu ZnSnS [CZTS], Cu ZnSnSe [CZTSe] and their alloys) are non-stoichiometric with Cu / (Zn + Sn) ≈ 0.8 and Zn / Sn ≈ 1.2. The fundamental cause is so far...
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A photoactive titanate with a stereochemically active Sn lone pair
Lee A. Burton, Aron Walsh
Dec 01, 2012
TiO 2 remains the most widely studied metal oxide for photocatalytic reactions. The standard approach to reduce the band gap of titania, for increasing the absorption of visible light, is anion modification. For example the...
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Oxidative Addition to Sn(II) Guanidinate Complexes

SnS, SnSe and SnTe are potentially important semiconductor materials. Here, we describe the application of chalcogen containing Sn IV guanidinate precursors for the production of tin(II) chalcogenide nanocrystals....

Published by:
A photoactive titanate with a stereochemically active Sn lone pair
Lee A. Burton, Aron Walsh
Dec 01, 2012
TiO 2 remains the most widely studied metal oxide for photocatalytic reactions. The standard approach to reduce the band gap of titania, for increasing the absorption of visible light, is anion modification. For example the...
Published by:
Structure Prediction of Li--Sn and Li--Sb Intermetallics for Lithium-ion Batteries Anodes.
M Mayo, AJ Morris
Jul 04, 2017
A variety of new stable and metastable Li–Sn and Li–Sb intermetallics are presented using the ab initio random structure searching (AIRSS) and species swapping methods. There include LiSn2–P4/mmm, Li2Sn3–P-1, Li7Sn9–P42/n...
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Phase Transformations and Phase Segregation during Potassiation of Sn x P y Anodes.
K-ion batteries (KIBs) have the potential to offer a cheaper alternative to Li-ion batteries (LIBs) using widely abundant materials. Conversion/alloying anodes have high theoretical capacities in KIBs, but it is believed that...
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Deposition of SnS Thin Films from Sn(II) Thioamidate Precursors
Two thioamide pro-ligands, R1N(H)C(S)R2 (R1 = t-Bu, R2 = i-Pr and R1 = i-Pr, R2 = i-Pr), were synthesized by treatment of the corresponding amides with Lawesson’s reagent. Reactions of [Sn{N(SiMe3)2}2] with two molar...
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Shape-controlled electrodeposition of tin crystals from Sn(II)-fluoroborate solutions
The shape evolution of mesoscopic tin crystals electrodeposited on boron-doped diamond (BDD) substrates is described as a function of the ion concentration and deposition potential. Concentrations of 5-100 mM Sn(II) in 1 M...
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Shape-controlled electrodeposition of tin crystals from Sn(II)-fluoroborate solutions
The shape evolution of mesoscopic tin crystals electrodeposited on boron-doped diamond (BDD) substrates is described as a function of the ion concentration and deposition potential. Concentrations of 5-100 mM Sn(II) in 1 M...
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Deposition of SnS Thin Films from Sn(II) Thioamidate Precursors
Two thioamide pro-ligands, R1N(H)C(S)R2 (R1 = t-Bu, R2 = i-Pr and R1 = i-Pr, R2 = i-Pr), were synthesized by treatment of the corresponding amides with Lawesson’s reagent. Reactions of [Sn{N(SiMe3)2}2] with two molar...
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The Type Ibn Supernova 2019kbj
Abstract Type Ibn supernovae (SNe) are a rare class of stellar explosions whose progenitor systems are not yet well determined. We present and analyze observations of the Type Ibn...
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Asia-Pacific Students' Awareness and Behaviour Regarding Social Networking in the Education Sector
Social networking (SN) technology has been presented to human beings as a means of communicating, collaborating, connecting, and cooperating to exchange knowledge, skills, news, chat, and to maintain contact with peers...
Virtual-reality exergaming improves performance during high-intensity interval training
Purpose: To determine if: i) mean power output and enjoyment of high-intensity interval training (HIIT) are enhanced by virtual-reality (VR)-exergaming (track mode) compared to standard ergometry (blank mode), ii) if mean power...
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Asia-Pacific Students' Awareness and Behaviour Regarding Social Networking in the Education Sector
Social networking (SN) technology has been presented to human beings as a means of communicating, collaborating, connecting, and cooperating to exchange knowledge, skills, news, chat, and to maintain contact with peers...
Testing the consistency of dust laws in SN Ia host galaxies
Abstract We apply BayeSN, our new hierarchical Bayesian model for the SEDs of Type Ia supernovae (SNe Ia), to analyse the griz light curves of 157 nearby SNe Ia (0.015 &lt; z...
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