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Results: 43
Epoxy-functionalised 4-vinylguaiacol for the synthesis of bio-based, degradable star polymers via a RAFT/ROCOP strategy
An epoxy derivative of a naturally occuring vinylphenolic compound, 4-vinylguaiacol (4VGEP), was used for the synthesis of a well-defined (Mw/Mn = 1.08–1.14), bio-based styrene-type polymer. Block copolymers of 4VGEP with...
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The CD8+ dendritic cell subset selectively endocytoses dying cells in culture and in vivo
Dendritic cells (DCs) are able in tissue culture to phagocytose and present antigens derived from infected, malignant, and allogeneic cells. Here we show directly that DCs in situ take up these types of cells after fluorescent...
Published by: Rockefeller University
Epoxy-functionalised 4-vinylguaiacol for the synthesis of bio-based, degradable star polymers via a RAFT/ROCOP strategy
An epoxy derivative of a naturally occuring vinylphenolic compound, 4-vinylguaiacol (4VGEP), was used for the synthesis of a well-defined (Mw/Mn = 1.08–1.14), bio-based styrene-type polymer. Block copolymers of 4VGEP with...
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Expanding the tools available for direct ortho cupration - Targeting lithium phosphidocuprates
Reaction of in situ generated lithium phosphides with 0.5 eq. Cu(i) is employed as a means of targeting lithium phosphidocuprates of either Gilman- or Lipshutz-type formulation - e.g., (R 2P) 2CuLi·n(LiX) (n = 0, 1). For R = Ph...
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Expanding the tools available for direct ortho cupration - Targeting lithium phosphidocuprates
Reaction of in situ generated lithium phosphides with 0.5 eq. Cu(i) is employed as a means of targeting lithium phosphidocuprates of either Gilman- or Lipshutz-type formulation - e.g., (R 2P) 2CuLi·n(LiX) (n = 0, 1). For R = Ph...
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Structural effects in lithiocuprate chemistry

TMPLi (TMP=2,2,6,6-tetramethylpiperidide) reacts with CuI salts in the presence of Et2O to give the dimers [{(TMP)2Cu(X)Li2(OEt2)}2] (X=CN, halide). In...

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Discovery of Protoclusters at z∼3.7 and 4.9
We have carried out follow-up spectroscopy on three overdense regions of g- and r-dropout galaxies in the Canada–France–Hawaii Telescope Legacy Survey Deep Fields, finding two new protoclusters at z = 4.898 and 3.721 and a...
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Structural effects in lithiocuprate chemistry

TMPLi (TMP=2,2,6,6-tetramethylpiperidide) reacts with CuI salts in the presence of Et2O to give the dimers [{(TMP)2Cu(X)Li2(OEt2)}2] (X=CN, halide). In...

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Lipshutz-type bis(amido)argentates for directed ortho argentation.
Bis(amido)argentate (TMP)2Ag(CN)Li2 (3, TMP-Ag-ate; TMP = 2,2,6,6-tetramethylpiperidido) was designed as a tool for chemoselective aromatic functionalization via unprecedented directed ortho argentation (DoAg). X-Ray...
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Discovery of Protoclusters at z∼3.7 and 4.9
We have carried out follow-up spectroscopy on three overdense regions of g- and r-dropout galaxies in the Canada–France–Hawaii Telescope Legacy Survey Deep Fields, finding two new protoclusters at z = 4.898 and 3.721 and a...
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Interrelation of the Environment of Lyα Emitters and Massive Galaxies at 2 < z < 4.5

We present a comparison of the spatial distributions of Lyα emitters (LAEs) and massive star-forming and quiescent galaxies (SFGs and QGs) at 2 < z < 4.5. We use the photometric redshift catalog to select SFGs and QGs...

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Statistical Correlation between the Distribution of Lyα Emitters and Intergalactic Medium Hi at z∼2.2 Mapped by the Subaru/Hyper Suprime-Cam

The correlation between neutral hydrogen (H I) in the intergalactic medium (IGM) and galaxies attracts great interest. We select four fields that include several coherently strong Lyα absorption systems at z ∼ 2.2 detected...

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Interrelation of the Environment of Lyα Emitters and Massive Galaxies at 2 &lt; z &lt; 4.5

We present a comparison of the spatial distributions of Lyα emitters (LAEs) and massive star-forming and quiescent galaxies (SFGs and QGs) at 2 < z < 4.5. We use the photometric redshift catalog to select SFGs and QGs...

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The Subaru HSC Galaxy Clustering with Photometric Redshift. I. Dark Halo Masses versus Baryonic Properties of Galaxies at 0.3≤z≤ 1.4
We present the clustering properties of low-z (z ≤ 1.4) galaxies selected by the Hyper Suprime-Cam Subaru Strategic Program Wide layer over 145 deg2. The wide-field and multiwavelength observation yields 5,064,770 galaxies at...
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A Wide and Deep Exploration of Radio Galaxies with Subaru HSC (WERGS). IX. The most overdense region at z ∼ 5 inhabited by a massive radio galaxy
We report on the galaxy density environment around a high-z radio galaxy (HzRG) at z = 4.72, HSC J083913.17+011308.1 (HSC J0839+0113), probed using an r-dropout Lyman break galaxy (LBG) sample from the Hyper Suprime-Cam Subaru...
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Faint Quasars Live in the Same Number Density Environments as Lyman Break Galaxies at z∼4
Characterizing high-z quasar environments is key to understanding the coevolution of quasars and the surrounding galaxies. To restrict their global picture, we statistically examine the g-dropout galaxy overdensity distribution...
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The Subaru HSC Galaxy Clustering with Photometric Redshift. I. Dark Halo Masses versus Baryonic Properties of Galaxies at 0.3≤z≤ 1.4
We present the clustering properties of low-z (z ≤ 1.4) galaxies selected by the Hyper Suprime-Cam Subaru Strategic Program Wide layer over 145 deg2. The wide-field and multiwavelength observation yields 5,064,770 galaxies at...
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