[Ni(NHC)2] as a scaffold for structurally characterized trans [H-Ni-PR2] and trans [R2P-Ni-PR2] complexes
Sara Sabater,
David Schmidt,
Heidi Schmidt,
Maximilian Kuntze-Fechner,
Thomas Zell,
Connie Isaac,
Nasir Rajabi,
Harry Grieve,
Will Blackaby,
John Lowe,
Stuart MacGregor,
Mary Mahon,
Udo Radius,
Michael Whittlesey
Sep 15, 2021
The addition of PPh2H, PPhMeH, PPhH2, P(para-Tol)H2, PMesH2 and PH3 to the two-coordinate Ni0 N-heterocyclic carbene species [Ni(NHC)2] (NHC=IiPr2, IMe4, IEt2Me2) affords a series of mononuclear, terminal phosphido nickel...