Predicting the self-assembly of a model colloidal crystal

D Klotsa, Robert L Jack

OAI: oai:purehost.bath.ac.uk:publications/24e2de5e-cffe-4723-a44c-45e490c195aa • DOI: https://doi.org/10.1039/c1sm05456b

We investigate the self-assembly (crystallisation) of particles with hard cores and isotropic, square-well interactions, using a Monte Carlo scheme to simulate overdamped Langevin dynamics. We measure correlation and response functions during the early stages of assembly, and we analyse the results using fluctuation-dissipation theorems, aiming to predict which systems will self-assemble successfully and which will get stuck in disordered states. The early-time correlation and response measurements are made before significant crystallisation has taken place, indicating that dynamical measurements are valuable in measuring a system's propensity for kinetic trapping.