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Transannular, decarboxylative Claisen rearrangement reactions for the synthesis of sulfur-substituted vinylcyclopropanes

D Craig, S J Gore, M I Lansdell, Simon Lewis, A V W Mayweg, A J P White

OAI: oai:purehost.bath.ac.uk:openaire_cris_publications/b920a092-0df1-423d-83dc-262a7c2709f7 • DOI: https://doi.org/10.1039/c0cc00976h

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Abstract

Unsaturated epsilon-lactones bearing an alpha-arylsulfonyl or alpha-arylsulfoximinyl substituent undergo stereoselective transannular, decarboxylative Claisen rearrangement to give substituted vinylcyclopropanes.