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Copper malonamide complexes and their use in azide-alkyne cycloaddition reactions
OAI: oai:purehost.bath.ac.uk:openaire_cris_publications/0773f4c5-7df8-45cc-aee7-036ca1bfb5bc • DOI: https://doi.org/10.1039/C5DT01312G
Abstract
We report a rare example of the malonamide functionality being used as a ligand in copper catalysis. We have ligated a homologous series of these O,O-chelating architectures to copper, investigated their structure and exploited them in azide–alkyne cycloaddition reactions for the step-growth synthesis of oligo(triazoles) and in the synthesis of small organic azoles.