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An Unusual Phase Transition Driven by Vibrational Entropy Changes in a Hybrid Organic–Inorganic Perovskite
Wenjun Wei, Keith Butler, Guoqiang Feng, Christopher J. Howard, Wei Li, Michael Carpenter, Peixiang Lu, Aron Walsh, Anthony K. Cheetham
OAI: oai:purehost.bath.ac.uk:openaire_cris_publications/33165282-ee08-4ab0-9802-d38fc72260eb • DOI: https://doi.org/10.1002/anie.201803176
Abstract
The driving forces for the phase transitions of ABX3 hybrid organic–inorganic perovskites have been limited to the octahedral tilting, order–disorder, and displacement. Now, a complex structural phase transition has been explored in a HOIP, [CH3NH3][Mn(N3)3], based on structural characterizations and ab initio lattice dynamics calculations. This unusual first‐order phase transition between two ordered phases at about 265 K is primarily driven by changes in the collective atomic vibrations of the whole lattice, along with concurrent molecular displacements and an unusual octahedral tilting. A significant entropy difference (4.35 J K−1 mol−1) is observed between the low‐ and high‐temperature structures induced by such atomic vibrations, which plays a main role in driving the transition. This finding offers an alternative pathway for designing new ferroic phase transitions and related physical properties in HOIPs and other hybrid crystals.