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On the appearance of nitrite anion in [PdX(OAc)L<sub>2</sub>] and [Pd(X)(C∧N)L] syntheses (X = OAc or NO<sub>2</sub>)
Pd 3(OAc) 5NO 2, an impurity in "Pd(OAc) 2" {formally Pd 3(OAc) 6}, emerges as a serious issue in the synthesis of pure Pd II complexes derived from Pd(OAc) 2, for example in our C-H activation precatalyst, Pd(OAc) 2(pip) 2 (pip...
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On the appearance of nitrite anion in [PdX(OAc)L<sub>2</sub>] and [Pd(X)(C∧N)L] syntheses (X = OAc or NO<sub>2</sub>)
Pd 3(OAc) 5NO 2, an impurity in "Pd(OAc) 2" {formally Pd 3(OAc) 6}, emerges as a serious issue in the synthesis of pure Pd II complexes derived from Pd(OAc) 2, for example in our C-H activation precatalyst, Pd(OAc) 2(pip) 2 (pip...
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3D sedimentary architecture showing the inception of an Ice Age
Abstract: Northeast Atlantic climate shifted into the Quaternary Ice Age around 2.6 M yr ago. Until now, however, the detailed changes associated with this inception of an Ice Age have remained obscure. New high-quality...
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Corinna PMG 655 (= P.Oxy. 2370) fr.1 l. 13 κόσμ[εισα λόγυ]ς
L Prauscello
May 02, 2017
0. Fr. 1 of P.Oxy. 2370 (= MP3 249; LDAB 573), published by Lobel in 1956, is so far the only papyrus fragment among those extant in Boeotian dialect1 whose authorship can be securely ascribed to Corinna thanks to the overlap...
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Hydration and N-acetyl-l-cysteine alter the microstructure of human nail and bovine hoof
This work aimed to (a) characterize the microstructure and porosity of human nail and bovine hoof by mercury intrusion porosimetry and SEM image analysis, (b) study the effects of hydration and of N-acetyl-l-cysteine treatment...
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Hydration and N-acetyl-l-cysteine alter the microstructure of human nail and bovine hoof
This work aimed to (a) characterize the microstructure and porosity of human nail and bovine hoof by mercury intrusion porosimetry and SEM image analysis, (b) study the effects of hydration and of N-acetyl-l-cysteine treatment...
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New C∧N∧C Bis-Cyclometalated Platinum(II) Complexes
The reaction of a new ligand, ethyl 2,6-diphenylisonicotinate (EtO(2)C-CAN boolean AND C-H(2)), with K(2)PtCl(4) in acetic acid affords the monocyclometalated complex [{(EtO(2)C-CANAC-H)Pt(mu-Cl)}(2)] (1), which transforms to...
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New C∧N∧C Bis-Cyclometalated Platinum(II) Complexes
The reaction of a new ligand, ethyl 2,6-diphenylisonicotinate (EtO(2)C-CAN boolean AND C-H(2)), with K(2)PtCl(4) in acetic acid affords the monocyclometalated complex [{(EtO(2)C-CANAC-H)Pt(mu-Cl)}(2)] (1), which transforms to...
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3D sedimentary architecture showing the inception of an Ice Age
Abstract: Northeast Atlantic climate shifted into the Quaternary Ice Age around 2.6 M yr ago. Until now, however, the detailed changes associated with this inception of an Ice Age have remained obscure. New high-quality...
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Three-dimensional structure of CaV3.1
Calcium entry through voltage-gated calcium channels has widespread cellular effects upon a host of physiological processes including neuronal excitability, muscle excitation-contraction coupling, and secretion. Using single...
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Separation and Selective Formation of Fullerene Adducts within an M$^{II}$$_{8}$L$_{6}$ Cage.
The self-assembly of 4-fold-symmetric porphyrins with Fe$^{II}$ or Zn$^{II}$ gave a new cubic M$^{II}$$_{8}$L$_{6}$ cage framework with electron-deficient walls. This cage bound C$_{60}$-indene or C$_{60}$-anthracene bisadducts...
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L-carnitine, a friend or foe for cardiovascular disease? A Mendelian randomization study.
BACKGROUND: L-carnitine is emerging as an item of interest for cardiovascular disease (CVD) prevention and treatment, but controversy exists. To examine the effectiveness and safety of L-carnitine, we assessed how genetically...
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Endocrine responses during overnight recovery from exercise
Nocturnal endocrine responses to exercise performed in the evening and the potential role of nutrition are poorly understood. To gain novel insight, 10 healthy men ingested carbohydrate with (C+P) and without (C) protein in a...
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Endocrine responses during overnight recovery from exercise
Nocturnal endocrine responses to exercise performed in the evening and the potential role of nutrition are poorly understood. To gain novel insight, 10 healthy men ingested carbohydrate with (C+P) and without (C) protein in a...
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Exploring Changes in Quasar Spectral Energy Distributions across C iv Parameter Space
Abstract We examine the UV/X-ray properties of 1378 quasars in order to link empirical correlations to theoretical models of the physical mechanisms dominating quasars as a...
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Neurodevelopmental regression, severe generalized dystonia, and metabolic acidosis caused by POLR3A mutations.
OBJECTIVE: To expand the clinical phenotype of POLR3A mutations by assessing the functional consequences of a missense and a splicing acceptor mutation. METHODS: We performed whole-exome sequencing for identification of likely...
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Second-Order <i>L</i> ∞ Variational Problems and the ∞-Polylaplacian

In this paper we initiate the study of second-order variational problems in L , seeking to minimise the L norm of a function of the hessian.We also derive and study the respective PDE arising as the...

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Localisation of an occult thyrotropinoma with $^{11}$C-methionine PET-CT before and after somatostatin analogue therapy
A 75-year-old woman presented to her local endocrine service with tiredness, palpitations, and enlargement of a longstanding goitre. Unexpectedly, her thyrotropin (thyroid-stimulating hormone [TSH]) concentration was not...
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Biosynthesis of Putrescine from L-arginine Using Engineered Escherichia coli Whole Cells
Putrescine, a biogenic amine, is a highly valued compound in medicine, industry, and agriculture. In this study, we report a whole-cell biocatalytic method in Escherichia coli for the production of putrescine, using...
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Floer Simple Manifolds and L-Space Intervals
J Rasmussen, SD Rasmussen
Feb 26, 2018
An oriented three-manifold with torus boundary admits either no L-space Dehn filling, a unique L-space filling, or an interval of L-space fillings. In the latter case, which we call “Floer simple,” we construct an invariant...
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L q -spectra of self-affine measures
Abstract: We study L q -spectra of planar self-affine measures generated by diagonal matrices. We introduce a new technique for constructing and understanding examples based on combinatorial estimates for the exponential growth...
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