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Electrochemically Driven C-H Hydrogen Abstraction Processes with the Tetrachloro-Phthalimido-N-Oxyl (Cl<sub>4</sub>PINO) Catalyst
Frank Marken, Mark A. Buckingham, Steven Bull, William Cunningham, Antoine Buchard, Andrea Folli, Damien Murphy
Aug 01, 2018
The radical redox mediator tetrachloro-phthalimido-N-oxyl (Cl4PINO) is generated at a glassy carbon electrode and investigated for the model oxidation of primary and secondary alcohols with particular attention to...
Electrochemically Driven C-H Hydrogen Abstraction Processes with the Tetrachloro-Phthalimido-N-Oxyl (Cl<sub>4</sub>PINO) Catalyst
Frank Marken, Mark A. Buckingham, Steven Bull, William Cunningham, Antoine Buchard, Andrea Folli, Damien Murphy
Aug 01, 2018
The radical redox mediator tetrachloro-phthalimido-N-oxyl (Cl4PINO) is generated at a glassy carbon electrode and investigated for the model oxidation of primary and secondary alcohols with particular attention to...
Combined SEM-CL and STEM investigation of green InGaN quantum wells
Abstract: The microstructure of green-emitting InGaN/GaN quantum well (QW) samples grown at different temperatures was studied using cross-section scanning transmission electron microscopy (STEM) and plan-view...
Combined SEM-CL and STEM investigation of green InGaN quantum wells
Abstract: The microstructure of green-emitting InGaN/GaN quantum well (QW) samples grown at different temperatures was studied using cross-section scanning transmission electron microscopy (STEM) and plan-view...
Nanocrystals of cesium lead halide perovskites (CsPbX3, X=Cl, Br, and I)
Loredana Protesescu, Sergii Yakunin, Maryna I. Bodnarchuk, Franziska Krieg, Riccarda Caputo, Christopher Holman Hendon, Ruoxi Yang, Aron Walsh, Maksym V. Kovalenko
Jun 10, 2015
Metal halides perovskites, such as hybrid organic-inorganic CH3NH3PbI3, are newcomer optoelectronic materials that have attracted enormous attention as solution-deposited absorbing layers in solar cells with power conversion...
Combined SEM-CL and STEM investigation of green InGaN quantum wells
Abstract
The microstructure of green-emitting InGaN/GaN quantum well (QW) samples grown at different temperatures was studied using cross-section scanning transmission electron...
Synthesis and structures of Cu-Cl-M adducts (M = Zn, Sn, Sb)
The novel bimetallic adducts [(Ph3P)2CuCl]2.ZnCl2 (1), {[(Me3P)CuCl]2.ZnCI2l}n (2)...
Synthesis and structures of Cu-Cl-M adducts (M = Zn, Sn, Sb)
The novel bimetallic adducts [(Ph3P)2CuCl]2.ZnCl2 (1), {[(Me3P)CuCl]2.ZnCI2l}n (2)...
Halide Mixing and Phase Segregation in Cs2AgBiX6 (X=Cl, Br, I) Double Perovskites from Cesium-133 Solid-State NMR and Optical Spectroscopy
Dominik J Kubicki, Marcin Saski, Stuart Macpherson, Krzysztof Galkowski, Janusz Lewiński, Daniel Prochowicz, Jeremy J Titman, Samuel D Stranks
Sep 29, 2020
All-inorganic double perovskites (elpasolites) are a promising potential alternative to lead halide perovskite in optoelectronic applications. While halide mixing is a well-established strategy for band gap tuning, little is...
Nanocrystals of cesium lead halide perovskites (CsPbX3, X=Cl, Br, and I)
Loredana Protesescu, Sergii Yakunin, Maryna I. Bodnarchuk, Franziska Krieg, Riccarda Caputo, Christopher Holman Hendon, Ruoxi Yang, Aron Walsh, Maksym V. Kovalenko
Jun 10, 2015
Metal halides perovskites, such as hybrid organic-inorganic CH3NH3PbI3, are newcomer optoelectronic materials that have attracted enormous attention as solution-deposited absorbing layers in solar cells with power conversion...
Theoretical Study of the Ti-Cl Bond Cleavage Reaction in TiCl4
In this work the kinetics of the TiCl4 <=> TiCl3 + Cl reaction is studied theoretically. A variable-reaction coordinate transition-state theory (VRC-TST) is used to calculate the high-pressure limit rate coefficients. The...
Local charge inhomogeneity and lithium distribution in the superionic argyrodites Li<sub>6</sub>PS<sub>5</sub><i>X</i> (<i>X</i> = Cl, Br, I)
Nicolò Minafra, Marvin Kraft, Tim Bernges, Cheng Li, Roman Schlem, Benjamin Morgan, Wolfgang Zeier
Aug 03, 2020
The lithium-argyrodites Li6PS5X (X = Cl, Br, I) exhibit high lithium-ion conductivities, making them promising candidates for use in solid-state batteries. These solid electrolytes can show...
Structure and Piezoelectricity Due to B Site Cation Variation in AB<sup>n+</sup>Cl<sub>n+2</sub>Hybrid Histammonium Chlorometallate Materials
Michael Wells, Jacob Hempel, Santosh Adhikari, Qingping Wang, Daniel Allen, Alison Costello, Chris Bowen, Sean Parkin, Christopher Sutton, Aron J. Huckaba
Nov 07, 2022
To provide new insights for understanding the influence of B site cations on the structure in chlorometallate materials of the form ABn+Cln+2, we report novel organic-inorganic hybrid metallates (OIHMs) incorporating...
Order–disorder, ferroelasticity and mobility of domain walls in multiferroic Cu–Cl boracite
Abstract: Domain walls in Cu–Cl boracite develop as a consequence of an improper ferroelastic, improper ferroelectric transition, and have attracted close interest because some are conductive and all can be mechanically written...
Dispersal and dispossession as bordering
Dispersal has acquired an increasingly central role within state-led border
control strategies in Europe and North Africa. Scholars have, however, tended
to apprehend dispersal in its geographical dimension, failing to...
Chloride channels are necessary for full platelet phosphatidylserine exposure and procoagulant activity.
Platelets enhance thrombin generation at sites of vascular injury by exposing phosphatidylserine during necrosis-like cell death. Anoctamin 6 (Ano6) is required for Ca(2+)-dependent phosphatidylserine exposure and is defective...
Reactivity of cationic α-diimine cyclopentadienyl nickel complexes towards AlEt₂Cl
Clara S. B. Gomes, Alejandro F. G. Ribeiro, Anabela C. Fernandes, Artur Bento, M. Rosário Ribeiro, Gabriele Kociok-Kohn, Sofia Pascu, M. Teresa Duarte, Pedro T. Gomes
Jul 21, 2017
The electronically saturated and air-stable complexes [Ni(η5-C5H5)(Mes-BIAN)][PF6] (1) and [Ni(η5-C5H5)(Mes-DAD)][PF6] (2) were found to behave as efficient catalyst precursors for the polymerisation of ethylene under mild...
The neural basis of hot and cold cognition in depressed patients, unaffected relatives, and low-risk healthy controls
BACKGROUND: Modern cognitive neuropsychological models of depression posit that negatively biased emotional ("hot") processing confers risk for depression, while preserved executive function ("cold") cognition promotes...
Structure and Piezoelectricity Due to B Site Cation Variation in AB<sup>n+</sup>Cl<sub>n+2</sub>Hybrid Histammonium Chlorometallate Materials
Michael Wells, Jacob Hempel, Santosh Adhikari, Qingping Wang, Daniel Allen, Alison Costello, Chris Bowen, Sean Parkin, Christopher Sutton, Aron J. Huckaba
Nov 07, 2022
To provide new insights for understanding the influence of B site cations on the structure in chlorometallate materials of the form ABn+Cln+2, we report novel organic-inorganic hybrid metallates (OIHMs) incorporating...
Exploring Language Teachers' Perceptions of Corpus Literacy Skills at Pre-Tertiary Level
Awatif Alruwaili
Jan 01, 2024
This study proposes five components of corpus literacy skills (CL) based on a survey of previous studies to investigate in-service teachers' perceived CL skills. Subsequently, the relationships among these components will be...
Published by: IGI Global Scientific Publishing
Local charge inhomogeneity and lithium distribution in the superionic argyrodites Li<sub>6</sub>PS<sub>5</sub><i>X</i> (<i>X</i> = Cl, Br, I)
Nicolò Minafra, Marvin Kraft, Tim Bernges, Cheng Li, Roman Schlem, Benjamin Morgan, Wolfgang Zeier
Aug 03, 2020
The lithium-argyrodites Li6PS5X (X = Cl, Br, I) exhibit high lithium-ion conductivities, making them promising candidates for use in solid-state batteries. These solid electrolytes can show...
Mechanisms of kinetic trapping in self-assembly and phase transformation
In self-assembly processes, kinetic trapping effects often hinder the formation of thermodynamically stable ordered states. In a model of viral capsid assembly and in the phase transformation of a lattice gas, we show how...
Order–disorder, ferroelasticity and mobility of domain walls in multiferroic Cu–Cl boracite
Abstract: Domain walls in Cu–Cl boracite develop as a consequence of an improper ferroelastic, improper ferroelectric transition, and have attracted close interest because some are conductive and all can be mechanically written...
Order–disorder, ferroelasticity and mobility of domain walls in multiferroic Cu–Cl boracite
Abstract: Domain walls in Cu–Cl boracite develop as a consequence of an improper ferroelastic, improper ferroelectric transition, and have attracted close interest because some are conductive and all can be mechanically written...
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