Matthew Neal '13, '14 is a recipient of a 2014 Knowles Science Teaching Foundation (KSTF) Teaching Fellowship. The Greenville, South Carolina, native will begin his first year of teaching this fall.
The first example of enantioselective S‐H insertion reactions of sulfoxonium ylides is reported. Under the influence of thiourea catalysis, excellent levels of enantiocontrol (up to 95% ee) and yields (up to 97%) are achieved...
The first example of enantioselective S‐H insertion reactions of sulfoxonium ylides is reported. Under the influence of thiourea catalysis, excellent levels of enantiocontrol (up to 95% ee) and yields (up to 97%) are achieved...
Monterey Submarine Canyon is a large, sinuous canyon off the coast of California, the upper reaches of which were the subject of an internal tide observational program using moored profilers and upward-looking moored ADCPs. The...
Pianist Matthew Manwarren, a professor of music at Winthrop University, will present a free solo piano recital on Sunday, Nov. 18, at 4 p.m. This concert is being presented as a celebration of the artist's 50th birthday. The...
"The Laramie Project" tells the story of the after-effects of the Matthew Shepard tragedy through real-life interviews. Show times are Oct 24-27 at 8 p.m. with a 2 p.m. showing Oct. 28.
The development of robust catalytic methods to assemble tertiary alkylamines provides a continual challenge to chemical synthesis. In this regard, transformation of a traditionally unreactive C-H bond, proximal to the nitrogen...
Monterey Submarine Canyon is a large, sinuous canyon off the coast of California, the upper reaches of which were the subject of an internal tide observational program using moored profilers and upward-looking moored ADCPs. The...
A synthetic study into the catalytic hydrogen/deuterium (H/D) exchange of 1° silanes, 2° silanes, and 3° siloxanes is presented, facilitated by iron-β-diketiminato complexes (1a and 1b). Near-complete H/D exchange is observed...
A synthetic study into the catalytic hydrogen/deuterium (H/D) exchange of 1° silanes, 2° silanes, and 3° siloxanes is presented, facilitated by iron-β-diketiminato complexes (1a and 1b). Near-complete H/D exchange is observed...
In his July 1984 interview with Michael Cooke, W. H. Winborne described his work with the Orangeburg Area Sickle Cell Anemia Foundation, the Family Health Center, and the outreach programs related to the foundation. Winborne...
The development of new chemical transformations based on catalytic functionalization of unactivated C-H bonds has the potential to simplify the synthesis of complex molecules dramatically. Transition metal catalysis has emerged...
A palladium(II)-catalyzed γ-C-H amination of cyclic alkyl amines to deliver highly substituted azetidines is reported. The use of a benziodoxole tosylate oxidant in combination with AgOAc was found to be crucial for controlling...
Current models for oxazaborolidine-catalyzed transition-state structures are determined by C–H···O–B and C–H···O═S formyl hydrogen bonding between the electrophile and catalyst. However, selectivity in the...
The selective C-H carbonylation of methylene bonds in the presence of traditionally more reactive methyl C-H and C(sp2)-H bonds in α-tertiary amines is reported. The exceptional selectivity is driven by the bulky α-tertiary...
Current models for oxazaborolidine-catalyzed transition-state structures are determined by C–H···O–B and C–H···O═S formyl hydrogen bonding between the electrophile and catalyst. However, selectivity in the...
Glutamate signalling is increasingly implicated across a range of psychiatric, neurological and pain disorders. Reliable methodologies are needed to probe the glutamate system and understand glutamate dynamics in vivo....
The neutral hydrogen (H I) content of dark matter haloes forms an intermediate state in the baryon cycle that connects the hot shock-heated gas and cold star-forming gas in haloes. Measurement of the relationship between H I...
Abstract: Searches for CP violation in the two-body decays Ds+→h+π0 and Ds+→h+η (where h+ denotes a π+ or K+ meson) are performed using pp collision data collected by the LHCb experiment corresponding to either 9 fb−1 or 6 fb−1...
The study of a selective palladium(ii)-catalyzed C(sp3)-H acetoxylation reaction on a class of cyclic alkyl amines is reported. Computational modelling and kinetic studies were used to provide support for a mechanism involving...
Social media is an important avenue for information dissemination and public communication in emergency management. Through social media content analysis and in-depth interviews, this study explores how county level emergency...
Searches for $CP$ violation in the two-body decays $D_{(s)}^{+}\rightarrow
h^{+}\pi^{0}$ and $D_{(s)}^{+} \rightarrow h^{+}\eta$ (where $h^{+}$ denotes a
$\pi^{+}$ or $K^{+}$ meson) are performed using $pp$ collision data...
The design of an enantioselective Pd(II)-catalyzed C–H amination reaction is described. The use of a chiral BINOL phosphoric acid ligand enables the conversion of readily available amines into synthetically valuable aziridines...