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On the appearance of nitrite anion in [PdX(OAc)L<sub>2</sub>] and [Pd(X)(C∧N)L] syntheses (X = OAc or NO<sub>2</sub>)
Pd 3(OAc) 5NO 2, an impurity in "Pd(OAc) 2" {formally Pd 3(OAc) 6}, emerges as a serious issue in the synthesis of pure Pd II complexes derived from Pd(OAc) 2, for example in our C-H activation precatalyst, Pd(OAc) 2(pip) 2 (pip...
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On the appearance of nitrite anion in [PdX(OAc)L<sub>2</sub>] and [Pd(X)(C∧N)L] syntheses (X = OAc or NO<sub>2</sub>)
Pd 3(OAc) 5NO 2, an impurity in "Pd(OAc) 2" {formally Pd 3(OAc) 6}, emerges as a serious issue in the synthesis of pure Pd II complexes derived from Pd(OAc) 2, for example in our C-H activation precatalyst, Pd(OAc) 2(pip) 2 (pip...
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New C∧N∧C Bis-Cyclometalated Platinum(II) Complexes
The reaction of a new ligand, ethyl 2,6-diphenylisonicotinate (EtO(2)C-CAN boolean AND C-H(2)), with K(2)PtCl(4) in acetic acid affords the monocyclometalated complex [{(EtO(2)C-CANAC-H)Pt(mu-Cl)}(2)] (1), which transforms to...
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New C∧N∧C Bis-Cyclometalated Platinum(II) Complexes
The reaction of a new ligand, ethyl 2,6-diphenylisonicotinate (EtO(2)C-CAN boolean AND C-H(2)), with K(2)PtCl(4) in acetic acid affords the monocyclometalated complex [{(EtO(2)C-CANAC-H)Pt(mu-Cl)}(2)] (1), which transforms to...
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Efficient Local Cloud-Based Solution for Diabetic Retinopathy Detection
Damage of blood vessels in retina due to diabetes is known as diabetic retinopathy. It is one of the one of the important origins of blindness for adults. Loss of vision can be avoided by detecting damage of retina (leaking...
A Comprehensive Performance Analysis of Various Classifier Models for Coronary Artery Disease Prediction
Cardio Vascular Diseases (CVD) is the major reason for the death of the majority of the people in the world. Earlier diagnosis of disease will reduce the mortality rate. Machine learning (ML) algorithms are giving promising...
Efficient iterative Hi-C scaffolder based on N-best neighbors.
BACKGROUND: Efficient and effective genome scaffolding tools are still in high demand for generating reference-quality assemblies. While long read data itself is unlikely to create a chromosome-scale assembly for most eukaryotic...
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Efficient iterative Hi-C scaffolder based on N-best neighbors
Abstract: Background: Efficient and effective genome scaffolding tools are still in high demand for generating reference-quality assemblies. While long read data itself is unlikely to create a chromosome-scale assembly for most...
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Influence of Soil Drought Stress on C, N and P Stoichiometry of Tamarix Chinensis Lour. in Yellow River Delta, China
Taking the one-year-old T. chinensis (Tamarix chinensis Lour.) in Yellow River Delta as the study object, the variations of C, N and P stoichiometry in T. chinensis under drought stress was studied using pot experiments. The...
Efficient iterative Hi-C scaffolder based on N-best neighbors.
BACKGROUND: Efficient and effective genome scaffolding tools are still in high demand for generating reference-quality assemblies. While long read data itself is unlikely to create a chromosome-scale assembly for most eukaryotic...
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Influence of Soil Drought Stress on C, N and P Stoichiometry of Tamarix Chinensis Lour. in Yellow River Delta, China
Taking the one-year-old T. chinensis (Tamarix chinensis Lour.) in Yellow River Delta as the study object, the variations of C, N and P stoichiometry in T. chinensis under drought stress was studied using pot experiments. The...
Circulating vitamin C and digestive system cancers
BACKGROUND & AIMS: Vitamin C is an antioxidant with a potential role in the prevention of digestive system cancers, but there is yet no consensus whether vitamin C has a causal role in these cancers. The aim of this study was to...
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Factors affecting the water retaining characteristics of lime and cement mortars in the freshly-mixed state
Desorptivity, the parameter which quantifies water retaining ability, has been determined for freshly-mixed natural hydraulic lime and cement mortars using a modified American Petroleum Institute pressure cell. The results show...
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Analysis of the abstraction of water from freshly mixed jointing mortars in masonry construction
Sharp front theory is used to derive an equation describing the time taken for a wet mortar joint to be dewatered by an absorbent substrate. The equation shows that the time taken to dewater a mortar joint is directly...
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