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On the appearance of nitrite anion in [PdX(OAc)L<sub>2</sub>] and [Pd(X)(C∧N)L] syntheses (X = OAc or NO<sub>2</sub>)
Pd 3(OAc) 5NO 2, an impurity in "Pd(OAc) 2" {formally Pd 3(OAc) 6}, emerges as a serious issue in the synthesis of pure Pd II complexes derived from Pd(OAc) 2, for example in our C-H activation precatalyst, Pd(OAc) 2(pip) 2 (pip...
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On the appearance of nitrite anion in [PdX(OAc)L<sub>2</sub>] and [Pd(X)(C∧N)L] syntheses (X = OAc or NO<sub>2</sub>)
Pd 3(OAc) 5NO 2, an impurity in "Pd(OAc) 2" {formally Pd 3(OAc) 6}, emerges as a serious issue in the synthesis of pure Pd II complexes derived from Pd(OAc) 2, for example in our C-H activation precatalyst, Pd(OAc) 2(pip) 2 (pip...
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New C∧N∧C Bis-Cyclometalated Platinum(II) Complexes
The reaction of a new ligand, ethyl 2,6-diphenylisonicotinate (EtO(2)C-CAN boolean AND C-H(2)), with K(2)PtCl(4) in acetic acid affords the monocyclometalated complex [{(EtO(2)C-CANAC-H)Pt(mu-Cl)}(2)] (1), which transforms to...
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New C∧N∧C Bis-Cyclometalated Platinum(II) Complexes
The reaction of a new ligand, ethyl 2,6-diphenylisonicotinate (EtO(2)C-CAN boolean AND C-H(2)), with K(2)PtCl(4) in acetic acid affords the monocyclometalated complex [{(EtO(2)C-CANAC-H)Pt(mu-Cl)}(2)] (1), which transforms to...
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Efficient Local Cloud-Based Solution for Diabetic Retinopathy Detection
Damage of blood vessels in retina due to diabetes is known as diabetic retinopathy. It is one of the one of the important origins of blindness for adults. Loss of vision can be avoided by detecting damage of retina (leaking...
S.C. Governor Appoints Gary Williams to Winthrop Board of Trustees
Winthrop University
Jan 01, 0001
HIGHLIGHTS Williams will immediately fill the seat held by Don Long, who was appointed to the seat by former S.C. Governor Nikki Haley. Williams is the CEO of Williams & Fudge Corp., a financial services firm in Rock Hill....
Published by: Winthrop University
A Comprehensive Performance Analysis of Various Classifier Models for Coronary Artery Disease Prediction
Cardio Vascular Diseases (CVD) is the major reason for the death of the majority of the people in the world. Earlier diagnosis of disease will reduce the mortality rate. Machine learning (ML) algorithms are giving promising...
Efficient iterative Hi-C scaffolder based on N-best neighbors.
BACKGROUND: Efficient and effective genome scaffolding tools are still in high demand for generating reference-quality assemblies. While long read data itself is unlikely to create a chromosome-scale assembly for most eukaryotic...
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Efficient iterative Hi-C scaffolder based on N-best neighbors
Abstract: Background: Efficient and effective genome scaffolding tools are still in high demand for generating reference-quality assemblies. While long read data itself is unlikely to create a chromosome-scale assembly for most...
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Influence of Soil Drought Stress on C, N and P Stoichiometry of Tamarix Chinensis Lour. in Yellow River Delta, China
Taking the one-year-old T. chinensis (Tamarix chinensis Lour.) in Yellow River Delta as the study object, the variations of C, N and P stoichiometry in T. chinensis under drought stress was studied using pot experiments. The...
Efficient iterative Hi-C scaffolder based on N-best neighbors.
BACKGROUND: Efficient and effective genome scaffolding tools are still in high demand for generating reference-quality assemblies. While long read data itself is unlikely to create a chromosome-scale assembly for most eukaryotic...
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Dorothy W. Williams '60 Endows Fund for Family and Consumer Sciences
Winthrop University
Jan 01, 0001
The Dorothy W. Williams Family and Consumer Sciences Fund will provide funds for the family and consumer sciences program to be used for scholarship awards; travel for student and faculty development; activities of the Winthrop...
Published by: Winthrop University
Influence of Soil Drought Stress on C, N and P Stoichiometry of Tamarix Chinensis Lour. in Yellow River Delta, China
Taking the one-year-old T. chinensis (Tamarix chinensis Lour.) in Yellow River Delta as the study object, the variations of C, N and P stoichiometry in T. chinensis under drought stress was studied using pot experiments. The...
Ruthenium(II)-Catalyzed C–H Functionalization Using the Oxazolidinone Heterocycle as a Weakly Coordinating Directing Group
Herein, we report the ruthenium-catalyzed ortho C–H alkenylation of a wide range of N-aryloxazolidinone scaffolds. Alkenylation was achieved with complete monoselectivity with a scope of 27 examples in 2-MeTHF. Yields ranged...
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Circulating vitamin C and digestive system cancers
BACKGROUND & AIMS: Vitamin C is an antioxidant with a potential role in the prevention of digestive system cancers, but there is yet no consensus whether vitamin C has a causal role in these cancers. The aim of this study was to...
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Ruthenium(II)-Catalyzed C–H Functionalization Using the Oxazolidinone Heterocycle as a Weakly Coordinating Directing Group
Herein, we report the ruthenium-catalyzed ortho C–H alkenylation of a wide range of N-aryloxazolidinone scaffolds. Alkenylation was achieved with complete monoselectivity with a scope of 27 examples in 2-MeTHF. Yields ranged...
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Tennessee Williams' ''A Streetcar Named Desire'' Returns to Winthrop Feb. 17
Winthrop University
Jan 01, 0001
Russell Luke, instructor of theatre, will direct Tennessee Williams' classic play, which runs Feb. 17-21. "A Streetcar Named Desire" was last performed at Winthrop in 1960.
Published by: Winthrop University
Oxidative stress, inflammation and recovery of muscle function after damaging exercise
There is no consensus regarding the effects of mixed antioxidant vitamin C and/or vitamin E supplementation on oxidative stress responses to exercise and restoration of muscle function. Thirty-eight men were randomly assigned to...
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