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Herein we report the synthesis and characterisation of a series of Zr(iv) 2,2'-bipyrrolidine-salan derived complexes and their exploitation for the ring opening polymerisation of rac-lactide to afford highly isotactically...
Herein we report the synthesis and characterisation of a series of Zr(iv) 2,2'-bipyrrolidine-salan derived complexes and their exploitation for the ring opening polymerisation of rac-lactide to afford highly isotactically...
We describe ion current rectification using a Polymer of Intrinsic Microporosity (PIM) based on Tröger's base (PIM-EA-TB). When deposited asymmetrically over one (or more) 20 μm diameter hole(s) in 6 μm thick poly(ethylene...
We describe ion current rectification using a Polymer of Intrinsic Microporosity (PIM) based on Tröger's base (PIM-EA-TB). When deposited asymmetrically over one (or more) 20 μm diameter hole(s) in 6 μm thick poly(ethylene...
A series of monopyrrolidine metal complexes have been prepared with the aim of elucidating structure-to-activity relationships for the ROP of lactide. Complexes of Li(I), Mg(II), Zn(II) and Zr(IV) were synthesised and fully...
Growing environmental concerns associated with the accumulation of plastic waste in the natural environment has incentivised considerable research into renewable alternatives, and more recently, alternative waste management...
A series of monopyrrolidine metal complexes have been prepared with the aim of elucidating structure-to-activity relationships for the ROP of lactide. Complexes of Li(I), Mg(II), Zn(II) and Zr(IV) were synthesised and fully...
There remains a major materials challenge in maintaining the performance of platinum (Pt) anode catalysts in fuel cells due to corrosion and blocking of active sites. Herein, we report a new materials strategy for improving...
The enzymeless glucose oxidation process readily occurs on nano-gold electrocatalyst at pH7, but it is highly susceptible to poisoning (competitive binding), for example from protein or chloride. Is it shown here that gold...
Growing environmental concerns associated with the accumulation of plastic waste in the natural environment has incentivised considerable research into renewable alternatives, and more recently, alternative waste management...
A water-insoluble Polymer with Intrinsic Microporosity (or PIM, here for the particular case of the Tröger Base system PIM-EA-TB, BET area ca. 103 m2 -1g) is demonstrated to act as a rigid...
Urine citrate analysis is relevant in the screening and monitoring of patients with prostate cancer and calcium nephrolithiasis. A sensitive, fast, easy, and low-maintenance electrochemiluminescence (ECL) method with...
Urine citrate analysis is relevant in the screening and monitoring of patients with prostate cancer and calcium nephrolithiasis. A sensitive, fast, easy, and low-maintenance electrochemiluminescence (ECL) method with...
A series of five iron and aluminum complexes bearing {ONSO} imine thiobis(phenolate) ligands have been prepared and applied to the ring-opening polymerization (ROP) of rac-lactide. Fe(1)Cl produced polylactide with a very...
A series of five iron and aluminum complexes bearing {ONSO} imine thiobis(phenolate) ligands have been prepared and applied to the ring-opening polymerization (ROP) of rac-lactide. Fe(1)Cl produced polylactide with a very...
Triphasic microporous materials (containing solid, liquid, and gas) are of interest in electrocatalysis. In this exploratory study, a polymer of intrinsic microporosity (PIM-EA-TB) is impregnated with PdCl4 2...
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